CYMEL® 1141 resin is a highly methylated/iso-butylated, carboxy-modified melamine crosslinker provided in iso-butanol. It's specifically crafted for electro-deposition primer formulations, excelling in corrosion protection and resistance. Featuring chelating groups, it forms colored compounds with heavy metal ions like iron and zinc. Consequently, it's recommended for use in dark single-coat applications or primers and is not suitable for pastel colors. Serving as a crosslinking agent, it finds application in primer formulations for automotive OEM coatings, coil coatings, industrial coatings, and metal coatings.

Functions: Crosslinking Agent

Chemical Family: Amino Resins

End Uses: Primer

Technical Data Sheet
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Knowde Enhanced TDS

Identification & Functionality

Chemical Family
CASE Ingredients Functions
Technologies

Features & Benefits

Performance Highlights

BENEFITS

  • Electrodeposition properties
  • Adhesion properties
  • Corrosion resistance

APPLICATION AREAS

  • Anodic electrodeposition
  • Cathodic electrodeposition
  • High solids primer formulations

Applications & Uses

Compatible Substrates & Surfaces
Coating Type

Properties

Physical Form
Appearance
Clear Liquid
Partially Soluble in
Aromatic Hydrocarbons
Typical Properties
ValueUnitsTest Method / Conditions
Colormax. 3Gardner
Non-Volatile Content83-87%wt
Free Formaldehyde Contentmax.0.4%
Viscosity (25°C)W-Y
Solubility & Compatibility

SOLUBILITY

Alcohol Complete
Esters Complete
Ketones Complete
Aromatic hydrocarbons Partial
Aliphatic hydrocarbons Insoluble
Water Insoluble

 

COMPATIBILITY

Acrylic resins Very good
Alkyd resins Very good
Polyester resins Very good
Epoxy resins Very good

Technical Details & Test Data

Backbone Polymer Selection

CYMEL 1141 resin contains mainly methoxymethyl and butoxymethyl functionalities making it a very effective crosslinker for backbone polymer resins containing hydroxyl, amide, or carboxyl functional groups, such as found on alkyd, polyester or acrylic resins. CYMEL 1141 is compatible with a wide range of backbone polymers providing films with superior adhesion and resistance properties. The effective equivalent weight of CYMEL 1141 typically ranges from 150-250 g/eq, however, its optimum loading should be determined experimentally for each formulation with consideration of the performance properties to be optimized.

Catalysis

Because of its high extent of alkylation, CYMEL 1156 resin responds best to sulfonic acid catalysts, like CYCAT® 4040 catalyst or CYCAT 600 catalyst. Generally, 0.5 to 1.0% of CYCAT 4040 catalyst on total resin solids of the formulation is sufficient to provide good cure at normal baking schedules (15-20 minutes at 120-150°C) in solvent-borne systems. Water-borne systems generally require temperatures of 150°C or higher to effect cure. Higher concentrations of catalyst might be necessary if there are basic pigments or additives present in the formulation.

Stability

FORMULATION STABILITY

The stability of formulated systems containing CYMEL 1141 resin can be enhanced by the addition of alcohols, amines or a combination of these. Low molecular weight primary alcohols such as methanol and n-butanol are most effective. Recommended amines are dimethylethanolamine (DMEA), triethylamine (TEA), or 2-amino-2-methyl-1-propanol (AMP) at a concentration of 0.5-1.0% on total binder solids. Package stability can also be enhanced by the use of a blocked acid catalyst such as CYCAT 4045 catalyst. For waterborne systems a pH of 7.5-8.5 should be maintained for adequate stability.

STORAGE STABILITY

CYMEL 1141 resin has a shelf life of 1080 days from the date of manufacture when stored at temperatures below 32°C. Although lower temperatures are not detrimental to stability, its viscosity will increase, possibly making the resin difficult to pump or pour. The viscosity will reduce again on warming, but care should be taken to avoid excessive local heat, as this can cause an irreversible increase in viscosity.

Packaging & Availability

Regional Availability
  • Africa
  • China
  • Europe
  • Latin America
  • Middle East
  • North America