PEROXAN DB is Di-tert-butyl peroxide 98%, Liquid.PEROXAN DB is used for the (co)polymerization of ethylene, styrene, acrylates and methacrylates. PEROXAN DB is also used for the production of controlled rheology polypropylene (CR-PP).PEROXAN DB is used for the curing of unsaturated polyester resins and polymerization of styrene alkyde mixtures.PEROXAN DB is used for the crosslinking of polyolefins as well as natural rubber and synthetic rubber.

Functions: Curing Agent, Initiator

Chemical Family: Peroxides

Compatible Polymers & Resins: Acrylics, Natural Rubbers (NR), Polyethylenes (PE), Polypropylenes (PP), Polystyrenes (PS), Unsaturated Polyester (UPE)

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Knowde Enhanced TDS

Identification & Functionality

Chemical Family
Plastics & Elastomers Functions
CAS No.
0110-05-04

Features & Benefits

Materials Features

Applications & Uses

Plastics & Elastomers End Uses
Recommended Applications

Due to its high volatility, PEROXAN DB requires precautions in handling and metering.

Polymerization of ethylene : PEROXAN DB is used for high pressure in both autoclave and tubular processes, usually in combination with other peroxides of varying degrees of activity. Temperature range: 240 to 280°C Light-off temperature at 2300 bar: 265°C

Polymerization of styrene: PEROXAN DB may be used in polymerization and copolymarization of styrene. In a mass process PEROXAN DB can be used to increase polymerization rates. Temperature range: 95 to 185°C Dosing: 0,02 to 0,1 phr

Polymerization of acrylates and methacrylates: PEROXAN DB can be used as initiator for the solution, bulk and suspension (co)polymerization of acrylates and methacrylates. Temperature range (solution polym.): 130 to 175°C Dosing: 0,05 to 0,1 phr

Controlled rheology polypropylene (CR-PP) in an extrusion process: PEROXAN DB allows great flexibility in controlling the melt flow index (MFI) of polypropylene. Small changes in either peroxide concentration or process temperature can produce significantly different MFIs. The MFI increases with the peroxide level. Temperature range: 200 to 220°C Dosing: 0,01 to 0,1 phr

Properties

Physical Form
Appearance
Clear Liquid
Typical Properties
ValueUnitsTest Method / Conditions
Active oxygen assaymin. 10.72%
Density at 20°C0.8g/cm³
Molecular Weight146.2
Peroxide assaymin. 98%

Regulatory & Compliance

Certifications & Compliance

Technical Details & Test Data

Half Life Information
t ½ 10 h 1 h 1 min
bei121°C 141°C 183°C

 

Major Decomposition Products
  • Acetone
  • Methane
  • tert-Butanol

Safety & Health

Safety Characteristics
Flash point <6°C
SADT 80°C

 

Packaging & Availability

Packaging Type
Packaging Information
  • 20kg container
  • 154kg drum

Storage & Handling

Shelf Life
6 Months
Product Handling and Storage
  • Maximum storage temperature (Ts max) : 30°C
  • Storage stability as from date of delivery : 6 months
  • Keep packaging tightly closed in a well ventilated place at indicated storage temperature. Keep away from reducing agents e.g. amines, acids, alkalis, heavy metal compounds (e.g. accelerators, driers, metal soaps). Never weigh out in storage room. Oxidizing agent. Decomposes violently under the influence of heat or by contact with reducing agent. Never mix with accelerators. Organic Peroxides are more or less stable products but will decompose under the influence of heat. To minimize a loss of quality during storage, it is important that the recommended maximum storage temperature is not exceeded. If a minimum storage temperature is given, an undesirable process such as a solidification or phase separation, is known to occur below this temperature.
  • Please refer to the material safety data sheet (MSDS) for information concerning safe storage, use and handling of PEROXAN DB.