ZEROL HD46 is a fully formulated ISO VG46 grade polyalkylene glycol lubricant designed specifically for application with HFO refrigerant R1234yf in mobile air conditioning (MAC) systems. The product is a speciality double end-capped PAG, and is manufactured to exacting standards of high double end-capping efficiency.

Product Type: Oil

Application Area: Compressors

Features: Chemical Resistant, High Temperature Strength, High Viscosity Index

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Identification & Functionality

Product Type

Features & Benefits

Key Attributes
  • Optimized miscibility in HFO refrigerant R1234yf.
  • Superior lubricity compared to alternative lubricant types, including ‘single end-capped’ PAG products, and di-capped PAGs with lower di-capped material content.
  • Exceptional Viscosity Index (VI) – The high VI enhances compressor life by ensuring efficient running at temperature extremes. The high VI may also allow the user to select a lower viscosity fluid than typically used, with associated power usage savings.
  • Good high temperature and chemical stability, even in presence of water, resulting in system lifetime extension and reduced maintenance costs.
  • Low hygroscopicity (tendency to absorb moisture) compared to alternative PAG products with lower di-capping content and vastly superior to single end capped PAGs
  • Formulating expertise – ZEROL HD46 series contain optimized additive technology to provide additional corrosion protection within the a/c system, to further enhance the extreme pressure and antiwear performance of the PAG, and to maximize fluid lifetime by ensuring against thermal or oxidative deterioration of the lubricant.
  • Excellent electrical resistivity properties for electrically driven systems.

Applications & Uses

Markets
Application Area
Product Applications

ZEROL HD46 is suitable for use in both belt and electrically driven compressors utilizing R1234yf, and is also fully suitable for use in R134a belt-driven and electric MAC compressors.

Properties

ISO Viscosity Grade
Appearance
Clear to slightly hazy, free of visible particles
Physical Properties
ValueUnitsTest Method / Conditions
Viscosity (at 40°C)46.0cSt
Viscosity (at 100°C)10.0cSt
Viscosity Index215.0
Flash Point (COC)min. 230°CASTM D92
Specific Gravity (at 20°C)0.99g/cm3ASTM D1298
Pour Pointmax. -25°CASTM D97
Typical Properties
ValueUnitsTest Method / Conditions
Viscosity (at 40°C)42.0 - 48.0cSt
Colormax. 1Gardner
Water Contentmax. 300ppm
Total Acid Valuemax. 0.03mgKOH/gASTM D664
Pour Pointmax. -25°CASTM D97
Capping Efficiencymin. 85%

Regulatory & Compliance

Certifications & Compliance

Technical Details & Test Data

Extreme Pressure Performance

The table below illustrates the results of extreme pressure lubricity tests conducted on ZEROL® HD 46, compared to a commercial standard ISO VG 46 di-capped lubricant, using FALEX test method ASTM D3233.

Falex Failure Load (lb) higher is better Method ASTM D3233 ZEROL HD46 Typical di-capped PAG ISO VG46 (“ND8”)
Fe blocks/Fe pins (air atmosphere, 20°C) 1000 750
Fe blocks/Fe pin (R1234yf atmosphere, 20°C) 1000 1000
Al blocks/Fe pin (R1234yf atmosphere, 20°C) 2250 1500
Fe blocks/Fe pin (R1234yf atmosphere, 160°C) 1000 500
Al blocks/Fe pin (R1234yf atmosphere, 160°C) 1500 1250
Falex Block Wear (mg) lower is better Fe blocks/Fe pin (R1234yf atmosphere, 20°C) 800lb load, 20 minutes. 17.5 Failed on Initial Loading
Al blocks/Fe pin (R1234yf atmosphere, 20°C) 800lb load, 20 minutes. 6.5 30.5

 

Competitive Analysis

 

Method ASTM D3233 ZEROL HD-46 Competitive OE ND-12 Aftermarket Blend
50%/50% HD-46/ND-12
Fe blocks/Fe pin (R1234yf atmosphere, 50°C) 1000 1000 1000

 

 

Antiwear Performance

Using the 4-ball wear test (ASTM D4172), the performance of ZEROL® HD46 is compared to a typical commercial di-capped PAG:

 

4-Ball Test Data (ASTM D4172) ZEROL HD46 Typical di-capped PAG ISO VG46 (“ND8”)
40kg load, 1 hour, wear scar (mm) 0.53 0.92

 

Sealed Glass Tube data

The chemical, thermal and hydrolytic stability of ZEROL® HD46  has been evaluated using ASHRAE 97 sealed glass tube testing. Testing was conducted under standard conditions of 50/50 wt/wt R1234yf/lubricant with 1000ppm & 30,000ppm water at 175°C, for 14 days, and at 190°C for 24 hours. An absence of corrosive or oxidation products on metal coupons (Cu, Al, Fe), combined with excellent color retention, and low post-test TAN values for the lubricant, confirms highest levels of product stability for ZEROL® HD 46 compared to other commercially available standard grades. Detailed test data is available upon specific request to Shrieve.

 

Miscibility Curves

Miscibility of ZEROL® HD46 in R1234yf refrigerant has been evaluated in accordance with ASHRAE 86 methodology to measure the Critical Solution Temperature (CST) as it varies with lubricant concentration in the refrigerant. Detailed test data is available upon specific request to Shrieve.

 

Electrical Properties

ZEROL® HD46 achieves electrical property resistance requirements for hermetic electrically driven compressors. ZEROL HD products have been applied in automotive and industrial air conditioning systems as well as refrigeration systems with electrically driven compressors. The data below demonstrates the viability of the product.

 

Property OEM Requirement ZEROL® HD46 Standard PAG Standard POE
Dielectric Strength
(ASTM D877)
35 kV 38 kV 30 kV 42 kV
Electrical Resistivity (IEC247) 109 Ohm-cm 1010 Ohm-cm 108 Ohm-cm 1011 Ohm-cm

 

Conclusion

ZEROL® HD46 is an extremely high quality di-capped PAG mobile air conditioning compressor lubricants, based on novel double end-capped PAG performance and developed specifically for use in R1234yf belt-driven and electric MAC compressors. Zerol HD46 may also be used in R134a belt-driven and electric MAC compressors. This technology is available in further ISO viscosity grades as required.