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Evonik
Dynasylan® 1122
Chemical Family:
Amines
Functions:
Sizing Agent, Adhesion Promoter, Coupling Agent, Crosslinking Agent, Surface Modifier
Applicable Processes:
Abrasives Manufacturing
Compatible Polymers & Resins:
Polyamides, Polyurethanes (PU), Polyethylenes (PE), Melamines & Melamine Formaldehydes (MF), Polypropylenes (PP), Polyvinyl Butyral (PVB), Polyvinyl Acetate (PVA), Furans, Phenolic Resins, Epoxies (EP), Polycarbonates (PC), Polybutylene Terephthalate (PBT), Ethylene Vinyl Acetate (EVA), Polyvinyl Chloride (PVC)
Dynasylan® 1122 is a secondary aminofunctional ethoxysilane, characterized by two symmetric silicone atoms. It functions as an adhesion promoter between inorganic materials (such as glass, metals, fillers) and organic polymers (including thermosets, thermoplastics, elastomers). In addition to its role as a surface modifier, Dynasylan® 1122 can be employed for the chemical modification of various substances.
Evonik
Dynasylan® 1505
Functions:
Crosslinking Agent, Impact Modifier, Adhesion Promoter, Surface Modifier, Coupling Agent
Applicable Processes:
Abrasives Manufacturing
Compatible Polymers & Resins:
Furans, Phenolic Resins, Melamines & Melamine Formaldehydes (MF)
Synonyms:
(3-Aminopropyl)diethoxymethylsilane, (3-Aminopropyl)methyldiethoxysilane, (Aminopropyl)methyldiethoxysilane, 3-(Diethoxymethylsilanyl)propylamine, 3-(Diethoxymethylsilyl)-1-propanamine, 3-(Diethoxymethylsilyl)propan-1-amine, 3-(Diethoxymethylsilyl)propylamine, γ-Aminopropylmethyldiethoxysilane, γ-Diethoxymethylsilylpropylamine
Dynasylan® 1505 is an amino-functional silane which acts as an adhesion promoter between inorganic materials (for example glass, metals and fillers) and organic polymers (thermosets, thermoplastics and elastomers) and as a surface modifier. This liquid product finds its use in coatings, primers, and industrial additives like foundry resins. Compatible with glass and metal substrates, it's your go-to for various applications, from abrasives manufacturing to pipes and cables. Elevate your materials with Dynasylan® 1505.
Evonik
Dynasylan® DAMO-T
Chemical Name:
3- (2- Aminoethylamino) propyl] trimethoxysilane
CAS Number:
1760-24-3
Functions:
Surface Modifier, Sizing Agent, Crosslinking Agent, Coupling Agent, Adhesion Promoter
Chemical Family:
Organosilane
Synonyms:
(2-Aminoethyl)(3-(trimethoxysilyl)propyl)amine, (Ethylenediaminepropyl)trimethoxysilane, (Ethylenediaminopropyl)trimethoxysilane, (Trimethoxysilylpropyl)ethylenediamine, (β-Aminoethyl)-γ-aminopropyltrimethoxysilane, (γ-Ethylenediaminepropyl)trimethoxysilane, [3-(2-Aminoethylamino)propyl]trimethoxylsilane, [3-[(2-Aminoethyl)amino]propyl]trimethoxysilane, [N-(2-Aminoethyl)-γ-aminopropyl]trimethoxysilane, [γ-(β-Aminoethylamino)propyl]trimethoxysilane, 2-Aminoethylaminopropyltrimethoxysilane, 3-(N-Aminoethyl)aminopropyltrimethoxysilane, 3-(Trimethoxysilyl)propylethylenediamine, 3-[N-(2-Aminoethyl)amino]propyltrimethoxysilane, 3-Ethylenediaminopropyltrimethoxysilane, 6-Amino-4-azahexyltrimethoxysilane, Aminoethylaminopropyltrimethoxysilane, N 1-[3-(Trimethoxysilyl)propyl]-1,2-ethanediamine, N-(2-Aminoethyl)-3-(trimethoxysilyl)propylamine, N-(2-Aminoethyl)-3-aminopropyltrimethoxysilane, N-(Aminoethyl)aminopropyltrimethoxysilane, N-(Trimethoxysilylpropyl)ethylenediamine, N-(β-Aminoethyl)-3-aminopropyltrimethoxysilane, N-(β-Aminoethyl)-g-aminopropylmethyldimethoxysilane, N-(β-Aminoethyl)-γ-aminopropyltrimethoxysilane, N-[3-(Trimethoxysilyl)propyl]-1,2-ethanediamine, N-[3-(Trimethoxysilyl)propyl]-1,2-ethylenediamine, N-[3-(Trimethoxysilyl)propyl]ethylenediamine, N-Aminoethyl-3-aminopropyltrimethoxysilane, N-Aminoethyl-γ-aminopropyltrimethoxysilane, N1-[3-(Trimethoxysilanyl)propyl]ethane-1,2-diamine, Trimethoxy[3-[(2-aminoethyl)amino]propyl]silane, γ-(2-Aminoethyl)aminopropyltrimethoxysilane, γ-(Ethylenediamino)propyltrimethoxysilane, γ-Aminoethylaminopropyltrimethoxysilane
Dynasylan® DAMO-T is a bifunctional organosilane, equipped with two reactive amino groups and hydrolyzable inorganic methoxysilyl groups. With this dual reactivity, Dynasylan® DAMO-T can establish chemical bonds with both inorganic materials (such as glass, metals, fillers) and organic polymers (including thermosets, thermoplastics, elastomers). This makes it an effective adhesion promoter and surface modifier.
Evonik
Dynasylan® HYDROSIL 1153
Functions:
Sizing Agent, Adhesion Promoter, Coupling Agent, Surface Modifier
Applicable Processes:
Foundry
Compatible Polymers & Resins:
Polyamides, Melamines & Melamine Formaldehydes (MF), Acrylics, Polypropylenes (PP), Polyvinyl Acetate (PVA), Silicones, Furans, Phenolic Resins, Polycarbonates (PC), Polybutylene Terephthalate (PBT), Ethylene Vinyl Acetate (EVA), Polyvinyl Chloride (PVC)
Dynasylan® HYDROSIL 1153 is the ultimate adhesion promoter and surface modifier. Tailored for enhancing bonding between glass and metal, this silane is a game-changer for various applications. Whether in primers, foundry resins, or abrasives, it delivers. With benefits like improved strength, corrosion resistance, and high performance, Dynasylan® HYDROSIL 1153 takes your materials to the next level.
Evonik
Dynasylan® SIVO 214
Functions:
Surface Modifier, Coupling Agent, Sizing Agent, Crosslinking Agent, Adhesion Promoter
Dynasylan® SIVO 214 is an aminofunctional silane composition with enhanced crosslinking activity. It serves as an adhesion promoter, facilitating bonding between inorganic materials (such as glass, metals, fillers) and organic polymers (including thermosets, thermoplastics, elastomers). Additionally, it functions as a surface modifier and supports chemical modification of various substances.
Evonik
Dynasylan® HYDROSIL 1151
Functions:
Sizing Agent, Crosslinking Agent, Adhesion Promoter, Surface Modifier, Coupling Agent
Labeling Claims:
VOC-free
Applicable Processes:
Foundry
Dynasylan® HYDROSIL 1151 is the ultimate adhesion promoter and surface modifier. Tailored for enhancing bonding between glass and metal, this silane is a game-changer for various applications. Whether in primers, foundry resins, or abrasives, it delivers. With benefits like improved strength, corrosion resistance, and high performance, Dynasylan® HYDROSIL 1151 takes your materials to the next level.
Evonik
Dynasylan® 1189
Chemical Name:
N-(3-(Trimethoxysilyl)propyl)butylamine
CAS Number:
31024-56-3
Functions:
Adhesion Promoter, Surface Modifier, Sizing Agent, Crosslinking Agent, Coupling Agent
Chemical Family:
Amines
Applicable Processes:
Abrasives Manufacturing
Synonyms:
N-(3-Trimethoxysilylpropyl)butan-1-amine
Dynasylan® 1189 is a bifunctional silane, boasts a reactive secondary amine and hydrolyzable methoxysilyl groups. Its dual reactivity enables chemical binding to both inorganic materials (such as glass, metals, fillers) and organic polymers (like thermosets, thermoplastics, elastomers). Serving as an adhesion promoter, surface modifier, and catalyst for substance modification, Dynasylan® 1189 contributes to versatile applications.
Evonik
Dynasylan® AMMO
Chemical Name:
(3- Aminopropyl) trimethoxysilane
CAS Number:
13822-56-5
Functions:
Surface Modifier, Sizing Agent, Crosslinking Agent, Coupling Agent, Adhesion Promoter
Chemical Family:
Organosilane
Applicable Processes:
Foundry
Synonyms:
(3-Aminopropyl)trimethoxysilane, (γ-Aminopropyl)trimethoxysilane, 3-(Trimethoxysilanyl)propylamine, 3-(Trimethoxysilyl)-1-propanamine, 3-(Trimethoxysilyl)-1-propyl amine, 3-(Trimethoxysilyl)propylamine, Aminopropyltrimethoxysilane, Trimethoxy(3-aminopropyl)silane, γ-Aminopropyl trimethoxysilane
Dynasylan® AMMO is a bifunctional organosilane, presents a reactive primary amine and hydrolyzable inorganic methoxysilyl groups. Its dual reactivity enables chemical bonding to both inorganic materials (e.g., glass, metals, fillers) and organic polymers (e.g., thermosets, thermoplastics, elastomers). Functioning as an adhesion promoter and surface modifier, Dynasylan® AMMO is a clear, colorless liquid with an amine-like odor. It shows solubility in alcohols and aliphatic and aromatic hydrocarbons.
Evonik
Dynasylan® AMEO
Functions:
Surface Modifier, Coupling Agent, Sizing Agent, Crosslinking Agent, Adhesion Promoter
Chemical Family:
Organosilane
Applicable Processes:
Abrasives Manufacturing
Dynasylan® AMEO is a bifunctional silane, encompassing a reactive primary amino group and hydrolyzable ethoxysilyl groups. Its dual reactivity enables Dynasylan® AMEO to establish chemical bonds with both inorganic materials (e.g., glass, metals, fillers) and organic polymers (such as thermosets, thermoplastics, elastomers). It serves as an adhesion promoter, crosslinker, and surface modifier.
Evonik
Dynasylan® 1401
Functions:
Crosslinking Agent, Impact Modifier, Adhesion Promoter, Surface Modifier, Coupling Agent
Compatible Polymers & Resins:
Furans, Phenolic Resins
Synonyms:
(2-Aminoethyl)-γ-aminopropylmethyldimethoxysilane, (N-β-Aminoethyl-γ-aminopropyl)dimethoxymethylsilane, [(Aminoethylamino)propyl]methyldimethoxysilane, [3-[(2-Aminoethyl)amino]propyl]methyldimethoxysilane, [3-[N-(2-Aminoethyl)amino]propyl]dimethoxymethylsilane, 2-(Aminoethyl)-3-aminopropyldimethoxysilane, 2-Aminoethyl-3-aminopropylmethyldimethoxysilane, Methyldimethoxy(β-aminoethyl-γ-aminopropyl)silane, N 1-[3-(Dimethoxymethylsilyl)propyl]-1,2-ethanediamine, N-(2-Aminoethyl)-3-aminopropylmethyldimethoxysilane, N-(2-Aminoethyl)-N-[3-(dimethoxymethylsilyl)propyl]amine, N-(2-Aminoethyl)-γ-aminopropylmethyldimethoxysilane, N-(β-Aminoethyl)-γ-aminopropylmethyldimethoxysilane, N-[3-(Dimethoxymethylsilyl)propyl]ethylenediamine, N-[3-(Methyldimethoxysilyl)propyl]ethylenediamine, N-Aminoethyl-3-aminopropyl-dimethoxymethylsilane, N-Aminoethyl-3-aminopropylmethyldimethoxysilane, N-Aminoethyl-γ-aminopropylmethyldimethoxysilane, N-β-(Aminoethyl)-γ-aminpropylmethyldimethoxysilane, β-Aminoethyl-(γ-aminopropyl)methyldimethoxysilane, γ-(β-Aminoethyl)aminopropylmethyldimethoxysilane
Dynasylan® 1401 is a bifunctional organosilane, incorporates reactive amino groups and hydrolyzable inorganic methoxysilyl groups. Its dual reactivity facilitates chemical binding to both inorganic materials (e.g., glass, metals, fillers) and organic polymers (including thermosets, thermoplastics, elastomers). This compound functions as an adhesion promoter, surface modifier, and reactant for product modification, offering a multifunctional solution.
Gelest Inc.
Gelest SIA0611.0
Chemical Family:
Silanes
Functions:
Coupling Agent
Compatible Polymers & Resins:
Furans, Melamines & Melamine Formaldehydes (MF), Epoxies (EP), Phenol Formaldehyde (PF), Polyvinyl Butyral (PVB)
Synonyms:
(3-Aminopropyl)trimethoxysilane, (γ-Aminopropyl)trimethoxysilane, 3-(Trimethoxysilanyl)propylamine, 3-(Trimethoxysilyl)-1-propanamine, 3-(Trimethoxysilyl)-1-propyl amine, 3-(Trimethoxysilyl)propylamine, Aminopropyltrimethoxysilane, Trimethoxy(3-aminopropyl)silane, γ-Aminopropyl trimethoxysilane
Gelest 3-AMINOPROPYLTRIMETHOXYSILANE (SIA0611.0) has superior reactivity in the vapor phase and non-aqueous surface treatments. This product functions as a coupling agent.
Dar-Tech Inc.
Access Rudolf Organosilane S 301
Chemical Family:
Silanes
Functions:
Coupling Agent
Compatible Polymers & Resins:
Polyesters, Polyurethanes (PU), Melamines & Melamine Formaldehydes (MF), Polyamides, Phenolic Resins, Polyvinyl Butyral (PVB), Urea Formaldehyde (UF), Silicones, Polysulfide Rubber, Epoxies (EP), Cellulose & Cellulosics, Polyolefins, Acrylics, Nitrocellulose, Chloroprene Rubber (CR), Furans
Synonyms:
(3-Mercaptopropyl)trimethoxysilane, (3-Thiopropyl)trimethoxysilane, (γ-Mercaptopropyl)trimethoxysilane, 3-(Sulfanylpropyl)trimethoxysilane, 3-(Trimethoxysilyl)-1-propanethiol, 3-(Trimethoxysilyl)propanethiol, 3-(Trimethoxysilyl)propyl mercaptan, 3-Mercaptopropyl trimethoxylsilane, 3-MPTMS, Trimethoxy-3-mercaptopropylsilane, γ-Thiolpropyltrimethoxysilane
Access Rudolf Organosilane S 301 is a versatile organosilane coupling agent that can improve the performance of adhesives, sealants, coatings, and other materials. Its unique chemical structure allows it to provide improved bonding and adhesion to substrates such as glass, metals, and organic surfaces. Access Rudolf Organosilane S 301 can also enhance the durability and weather resistance of materials by providing a protective coating. With its excellent properties and versatility, Access Rudolf Organosilane S 301 is a valuable tool for formulators looking to enhance the performance of their products.
Dar-Tech Inc.
Access Rudolf Organosilane G 302 - Ethoxy
Chemical Family:
Organosilane
Functions:
Adhesion Promoter, Coupling Agent
Compatible Polymers & Resins:
Polystyrenes (PS), Polyesters, Polyurethanes (PU), Melamines & Melamine Formaldehydes (MF), Polyamides, Phenolic Resins, Urea Formaldehyde (UF), Polysulfide Rubber, Epoxies (EP), Polyolefins, Acrylics, Furans, Unsaturated Polyester (UPE)
Synonyms:
[[3-(Triethoxysilyl)propoxy]methyl]oxirane, [3-(Glycidoxy)propyl]triethoxysilane, [3-(Glycidyoxy)propyl]triethoxysilane, 2-[[3-(Triethoxysilyl)propoxy]methyl]oxirane, 3-(2,3-Epoxypropoxy)propyltriethoxysilane, 3-(2,3-Epoxypropyloxy) propyl triethoxy silane, 3-(Glycidyloxypropyl)triethoxysilane, 3-(Triethoxysilyl)propyl glycidyl ether, 3-Glycydoxylpropyltriethoxysilane, Epoxypropoxypropyltriethoxysilane, Glycidyl 3-(triethoxysilyl)propyl ether, Triethoxy(3-glycidoxypropyl)silane, Triethoxy[3-(2-oxiranylmethoxy)propyl]silane, γ-(2,3-Epoxypropoxy)propyltriethoxysilane, γ-(Glycidyloxypropyl)triethoxysilane, γ-Glycidoxypropyltriethoxysilane, γ-Glycydoxypropyltriethoxysilane
Access Rudolf Organosilane G 302 - Ethoxy is an innovative silane coupling agent that improves the adhesion and crosslinking of various coatings and adhesives. This multifunctional product is specifically designed to enhance the durability and performance of the final product, making it an ideal choice for many industries, including automotive, aerospace, and construction. With its unique ethoxy functionality, Access Rudolf Organosilane G 302 - Ethoxy offers superior performance compared to other silane coupling agents.
Dar-Tech Inc.
Access Rudolf Organosilane A311 3-Aminopropylmethyldimethoxysilane
Chemical Family:
Silanes
Functions:
Coupling Agent
Compatible Polymers & Resins:
Polyesters, Polyurethanes (PU), Melamines & Melamine Formaldehydes (MF), Polyamides, Phenolic Resins, Polyvinyl Butyral (PVB), Urea Formaldehyde (UF), Silicones, Polysulfide Rubber, Epoxies (EP), Cellulose & Cellulosics, Polyolefins, Acrylics, Nitrocellulose, Chloroprene Rubber (CR), Furans
Access Rudolf Organosilane A311 3-Aminopropylmethyldimethoxysilane is a versatile silane coupling agent with 3-aminopropylmethyldimethoxysilane as its active ingredient. It improves adhesion and durability of various organic and inorganic substrates, particularly those containing hydroxyl groups. It can be used as a Intermediate, adhesives, sealants and laboratory chemical.
Dar-Tech Inc.
Access Rudolf Organosilane A 302T2
Chemical Name:
(3- Aminopropyl) triethoxysilane
Functions:
Coupling Agent, Intermediate, Adhesion Promoter
CAS Number:
919-30-2
Chemical Family:
Organosilane
Synonyms:
(3-Aminopropyl)triethoxylsilane, (3-Aminopropyl)triethoxysilane, (Aminopropyl)triethoxysilane, (γ-Aminopropyl)triethoxylsilane, (γ-Aminopropyl)triethoxysilane, 3-(Triethoxysilanyl)propylamine, 3-(Triethoxysilyl)-1-propanamine, 3-(Triethoxysilyl)-1-propylamine, 3-(Triethoxysilyl)propanamine, 3-(Triethoxysilyl)propane-1-amine, 3-(Triethoxysilyl)propylamine, NSC 95428, Triethoxy(3-aminopropyl)silane, Triethoxy(γ-aminopropyl)silane, γ-Aminpropyltriethoxysilane, γ-Triethoxysilylpropylamine
Access Rudolf Organosilane A 302T2 is an organosilane coupling agent that is designed to enhance the adhesion between inorganic materials and organic polymers. This coupling agent is specially designed for use in high-temperature applications and offers excellent thermal stability. It can improve the mechanical properties of the final product and can be used in a wide range of applications such as sealants, adhesives, and coatings.
Dar-Tech Inc.
Access Rudolf Organosilane S 302
Chemical Family:
Silanes
Functions:
Coupling Agent
Compatible Polymers & Resins:
Polyesters, Polyurethanes (PU), Melamines & Melamine Formaldehydes (MF), Polyamides, Phenolic Resins, Polyvinyl Butyral (PVB), Urea Formaldehyde (UF), Silicones, Polysulfide Rubber, Epoxies (EP), Cellulose & Cellulosics, Polyolefins, Acrylics, Nitrocellulose, Chloroprene Rubber (CR), Furans
Synonyms:
(3-Mercaptopropyl)triethoxysilane, (3-Thiopropyl)triethoxysilane, (γ-Mercaptopropyl)triethoxysilane, 3-(Triethoxysilyl)-1-propanethiol, 3-(Triethoxysilyl)propyl mercaptan, Triethoxy(3-mercaptopropyl)silane
Access Rudolf Organosilane S 302 is a silane coupling agent that enhances adhesion and wetting properties of coatings, adhesives, and sealants. S302 improves the performance of coatings and composites by providing excellent water resistance, abrasion resistance, and adhesion. It is suitable for use on various substrates, including glass, metal, and plastics.
Dar-Tech Inc.
Access Rudolf Organosilane A 302T1
Chemical Family:
Silanes
Compatible Polymers & Resins:
Cellulose & Cellulosics, Nitrocellulose, Urea Formaldehyde (UF), Epoxies (EP), Furans, Polysulfide Rubber, Polyurethanes (PU), Chloroprene Rubber (CR), Polyolefins, Silicones, Melamines & Melamine Formaldehydes (MF), Polyamides, Acrylics, Polyvinyl Butyral (PVB), Phenolic Resins, Polyesters
Synonyms:
(3-Aminopropyl)triethoxylsilane, (3-Aminopropyl)triethoxysilane, (Aminopropyl)triethoxysilane, (γ-Aminopropyl)triethoxylsilane, (γ-Aminopropyl)triethoxysilane, 3-(Triethoxysilanyl)propylamine, 3-(Triethoxysilyl)-1-propanamine, 3-(Triethoxysilyl)-1-propylamine, 3-(Triethoxysilyl)propanamine, 3-(Triethoxysilyl)propane-1-amine, 3-(Triethoxysilyl)propylamine, NSC 95428, Triethoxy(3-aminopropyl)silane, Triethoxy(γ-aminopropyl)silane, γ-Aminpropyltriethoxysilane, γ-Triethoxysilylpropylamine
Access Rudolf Organosilane A 302T1 is an organosilane coupling agent that is designed to enhance the adhesion between inorganic materials and organic polymers. This coupling agent is specially designed for use in high-temperature applications and offers excellent thermal stability. It can improve the mechanical properties of the final product and can be used in a wide range of applications such as sealants, adhesives, and coatings.
USI Chemical America,LLC
USI Chemical Silane USi-1301
Chemical Family:
Silanes, Amines
Functions:
Adhesion Promoter, Coupling Agent, Dispersant, Surface Modifier
Compatible Polymers & Resins:
Furans
Features:
Increases Flexural Modulus, Water Resistant, Excellent Flexural Modulus, Corrosion Resistant, Improved Flexural Strength, Corrosion Resistance, Excellent Dispersibility, Water Resistance, Good Mechanical Properties, High Tensile Strength, High Modulus
Synonyms:
(3-Aminopropyl)trimethoxysilane, (γ-Aminopropyl)trimethoxysilane, 3-(Trimethoxysilanyl)propylamine, 3-(Trimethoxysilyl)-1-propanamine, 3-(Trimethoxysilyl)-1-propyl amine, 3-(Trimethoxysilyl)propylamine, Aminopropyltrimethoxysilane, Trimethoxy(3-aminopropyl)silane, γ-Aminopropyl trimethoxysilane
USI Chemical Silane USi-1301 functions as a surface modifier in fillers and pigments, where it improves the dispersibility of the filler and the mechanical properties - such as flexural strength, tensile strength and modulus of the composites. The silane also has its application as an adhesion promoter in formulations and primers & reduces the filler's sedimentation tendency in the uncured polymer. USi-1301 also greatly increases water (vapor) and corrosion resistance.
USI Chemical America,LLC
USI Chemical Silane USi-1302
Chemical Family:
Silanes, Amines
Functions:
Anti-Abrasion Agent, Adhesion Promoter, Surface Modifier, Coupling Agent, Dispersant
Product Type:
Primer
Synonyms:
(3-Aminopropyl)triethoxylsilane, (3-Aminopropyl)triethoxysilane, (Aminopropyl)triethoxysilane, (γ-Aminopropyl)triethoxylsilane, (γ-Aminopropyl)triethoxysilane, 3-(Triethoxysilanyl)propylamine, 3-(Triethoxysilyl)-1-propanamine, 3-(Triethoxysilyl)-1-propylamine, 3-(Triethoxysilyl)propanamine, 3-(Triethoxysilyl)propane-1-amine, 3-(Triethoxysilyl)propylamine, NSC 95428, Triethoxy(3-aminopropyl)silane, Triethoxy(γ-aminopropyl)silane, γ-Aminpropyltriethoxysilane, γ-Triethoxysilylpropylamine
USI Chemical Silane USi-1302 functions as a surface modifier in fillers and pigments, where it improves the dispersibility of the filler and the mechanical properties such as flexural strength, tensile strength and modulus of the composites. The silane also has its application as an adhesion promoter in formulations and primers & reduces the filler's sedimentation tendency in the uncured polymer. Silane USi-1302 also greatly increases water (vapor) and corrosion resistance.