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DOWSIL(TM) FA 4002 ID Silicone Acrylate

1 of 77 products in this brand
DOWSIL(TM) FA 4002 ID Silicone Acrylate is a film former designed for long lasting benefits in color cosmetics and skin care applications. It exhibits good compatibility with organic sunscreens, pigments and cosmetic ingredients. It provides sebum resistance, wash off resistance as well as comfort to wear. 

INCI Name: Acrylates/Polytrimethylsiloxymethacrylate Copolymer

Functions: Film Former

Benefit Claims: Anti-Pigment Transfer, Anti-Pollution, Color Stability, Comforting, Compatibility, Durable, Ease of Styling, Film Forming, Film Stability, Gloss, Long Lasting, Long Wear, Low Viscosity, Non-Drying, Non-Occlusive, Non-Tacky, Rub Resistant, SPF Enhancement, Sebum Absorption, Sebum Resistant, Shine & Radiance, Skin Protection, Skin Tightening, Smooth Feel, Substantivity, Transfer Resistant, Wash Off Resistance, Wrinkle Refinement

Labeling Claims: Allergen-free, Animal Products-free, BSE-free, CMR Substances-free, Endocrine Disruptor-free, Halal, Irradiation-free, Nanomaterials-free, Non-GMO, Not Listed In California Proposition 65, Palm Oil-free, Porcine-free, Preservative-free, SVHC Chemicals-free, Solvent-free, TSE-free, Vegan

Certifications & Compliance: EU Cosmetic Regulation 1223/2009 Compliant, Halal, IECIC (China), REACH (Europe)

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Identification & Functionality

Cosmetic Ingredients Functions
Composition

40% polymer in isododecane

Features & Benefits

Key Attributes
  • Film former
  • Compatibility with organic sunscreens, pigments and cosmetic ingredients
  • Additive in color cosmetics
  • Durable foundation with comfort to wear
  • Lipstick with long lasting, non-transfer and comfort properties
  • Wash off resistance
  • Sebum resistance and reduction
  • Non-occlusive
  • Flexible hold with bounce
Product Attributes for Skin Care and Color Cosmetics Applications
  • Permeable to semi-occlusive
  • Uniform and continuous
  • Long-lasting and removable
  • Comfort and sensory attributes

 

Formulator Advantages

  • Multiple film-forming technologies available for greater versatility
  • Multiple carriers available for greater formulation and manufacturingprocess flexibility
  • Good compatibility with common cosmetic ingredients, allowing incorporation in common product types, such as face care, sun care and color cosmetics

 

Consumer Advantages

  • Use of non-occlusive materials to preserve skin health and breathability
  • Variable film flexibility for wearing comfort and enjoyment
  • High sebum and water repellency as well as high rub-off resistance properties to provide outstanding long-lasting benefits and a rewarding daily skin-care experience

Applications & Uses

Application Format
Color Cosmetic Applications
Recommended Applications

Personal care applications including color cosmetic, sun care and hair care

Usage

This is a low viscosity fluid that is easily incorporated into a variety of personal care formulations.

Formulation Tips

When heat is used, the material should be processed in an enclosed vessel to prevent the isododecane from volatilizing; the vessel should be inerted at temperatures over 40°C (104°F).

Compatibility Chart

Compatibilities with common cosmetic ingredients.

Ratio of DOWSIL™ FA 4002 ID Silicone Acrylate: other material 1/9 5/5 9/1
Esters      
C12-15 alkyl benzoate Compatible Compatible Compatible
Caprilic/capric triglycerides Miscible Compatible Compatible
Coco-caprylate/caprate Miscible Compatible Compatible
Isopropyl isostearate Compatible Compatible Compatible
Isopropyl myristate Compatible Compatible Compatible
Isopropyl palmitate Compatible Compatible Compatible
Octylpalmitate Miscible Compatible Compatible
Octylstearate Miscible Compatible Compatible
Fatty alcohols/acids      
Octyldodecanol Miscible Miscible Compatible
Oleyl alcohol Miscible Miscible Compatible
Candelilla wax Not compatible Not compatible Compatible
Glycerides      
Glyceryl trioctanoate Compatible Compatible Compatible
Hydrocarbons      
Mineral oil Miscible Compatible Compatible
Synthetic polymer      
Polyethylene Compatible Compatible Compatible
Hydrophilics      
Ethanol absolute 98% Not compatible Compatible Compatible
Propylene glycol Miscible Compatible Compatible
Sunscreen agents      
Ethylhexyl dimethyl PABA Miscible Miscible Compatible
Ethylhexyl methoxycinnamate Compatible Compatible Compatible
Vegetable oils      
Castor oil Compatible Compatible Compatible
Jojoba oil Compatible Miscible Compatible
Lanolin oil Compatible Compatible Compatible
Sunflower oil Compatible Compatible Compatible
DOWSIL™ Materials      
DOWSIL™ 556 Cosmetic Grade Fluid Compatible Compatible Compatible
DOWSIL™ 593 Fluid Not compatible Miscible Not compatible
DOWSIL™ 2502 Cosmetic Fluid Not compatible Not compatible Compatible
DOWSIL™ 9040 Silicone Compatible Compatible Compatible
XIAMETER™ Materials      
XIAMETER™ PMX-200/10 Silicone cSt Miscible Miscible Compatible
XIAMETER™ PMX-200/350 Silicone cSt. Miscible Miscible Miscible
XIAMETER™ PMX-1401 Fluid Miscible Miscible Miscible
XIAMETER™ PMX-1413 Fluid Miscible Miscible Miscible
XIAMETER™ PMX-1501 Fluid Miscible Miscible Miscible
XIAMETER™ PMX-1503 Fluid Miscible Miscible Miscible

Properties

Physical Form
Appearance
Clear to slightly hazy
Typical Properties
ValueUnitsTest Method / Conditions
Viscosity (at 25°C)150mm²/sCorporate Test Method 004A
Viscosity (at 25°C)150.0mm²/sCorporate Test Method 004A
Refractive Index (at 25°C)1.43Corporate Test Method 0002
Non Volatile Content (1g, at 150°C, 3 hours)40%Corporate Test Method 0208
Non Volatile Content (1g, at 150°C, 3 hours)40.0%Corporate Test Method 0208
Flash Point40°CCorporate Test Method 0006, Open cup
Flash Point40.0°CCorporate Test Method 0006, Open cup
Cyclotetrasiloxane (D4) Contentmax. 0.1%
Cyclopentasiloxane (D5) Contentmax. 0.1%
Silicone Content40%

Regulatory & Compliance

Technical Details & Test Data

Technical Details

Evaporation profile of solvents - cyclopentasiloxane and isododecane

DOWSIL(TM) FA 4002 ID Silicone Acrylate - Technical Details

Foundation durability to evidence resistance of silicone acrylate copolymer compared to an MQ resin blend and a leading commercial product.

DOWSIL(TM) FA 4002 ID Silicone Acrylate - Technical Details - 1

Lipstick wear ability to evidence long lasting and comfort properties of silicone acrylate copolymer compared to an MQ resin blend and a leading commercial product.

DOWSIL(TM) FA 4002 ID Silicone Acrylate - Technical Details - 2

Technical Data - Rub-off Resistance

Resistance to rub-off of a film coated on VITRO-SKIN. Resistance measured by XRF after friction cycles using washability tester/felt band. Higher % value indicates greater resistance to rub-off.

DOWSIL(TM) FA 4002 ID Silicone Acrylate - Technical Data - Rub-Off Resistance

Skin Protection for the Urban Consumer - Preventive Approach

Silicones can form a film at the skin surface and shield it from environmental stressors by limiting the adhesion of pollution particles on skin and by reducing the cutaneous damage induced by pollutants such as ozone and cigarette smoke. See the difference adding DOWSIL(TM) FA 4002 ID Silicone Acrylate can make in reducing particulate adhesion.

DOWSIL(TM) FA 4002 ID Silicone Acrylate - Skin Protection For The Urban Consumer - Preventive Approach

Secret Shell formulation with 5% Dow silicone acrylate technology, CPF 1909 (in vitro testing on collagen substrate)

 

DOWSIL(TM) FA 4002 ID Silicone Acrylate - Skin Protection For The Urban Consumer - Preventive Approach - 1

Secret Shell formulation with 10.5% Dow silicone acrylate technology, CPF 2287 (in vivo testing on panelist forearm)

Skin Tightening with Comfort

A sensory panel evaluated DOWSIL(TM) MQ-1640 Flake Resin and DOWSIL(TM) FA 4002 ID Silicone Acrylate at 3% use levels in hydrogel formulations. A paired comparison test was used to assess each silicone. In both cases, the control offered instant tightening, but no lasting tightening sensation. In their respective formulations, the silicone materials provided instant as well as lasting tightening. Panelists also noted low tackiness and residue for silicone acrylate solution, along with an invisible film on the skin.

The addition of a small amount of DOWSIL(TM) HMW 2220 NonIonic Emulsion significantly improved the sensory profile with no impact on the skin tightening performance in combination with both silicone acrylates and resin film-formers.(Figure 1)

The tightening effect noted in sensory evaluations was confirmed with a Cutometer.

In Figure 2, the combination of silicone acrylate or silicone flake resin with the high molecular weight non-ionic emulsion shows a decrease in R0, which reflects an increase in skin firmness, then a tightening benefit.

As a complement to the series of laboratory tests, an in-use test was carried out with the help of 57 Dow employees who served as panelists. The female and male participants ranged in age from 20 to 70 and had typical Caucasian skin types. Two hydrogels were tested: one containing DOWSIL(TM) MQ-1640 Flake Resin (3%) and DOWSIL(TM) EP-9801 Hydro Cosmetic Powder (3%), and the second containing DOWSIL(TM) FA 4002 ID Silicone Acrylate (3%) and DOWSIL(TM) HMW 2220 Non-Ionic Emulsion (0.3%).

For both hydrogels, panelists confirmed the following findings of
the earlier evaluations:

  • They provided instant and lasting tightening.
  • The formulations were comfortable to wear, with a tightening sensation on skin.
  • There was a positive impact on wrinkle attenuation.
  • The products left an invisible film on skin. 

DOWSIL(TM) FA 4002 ID Silicone Acrylate - Skin Tightening With Comfort

Figure 1: Hydrogel formulation with silicone resin for skin tightening and emulsion of high molecular weight silicone for sensory enhancement.

DOWSIL(TM) FA 4002 ID Silicone Acrylate - Skin Tightening With Comfort - 1

Figure 2: Cutometer results from hydrogel formulations.

Packaging & Availability

Packaging Type
Packaging Information

This product is available in 150 kg drums and 15 kg pails. Samples are available in 500 g bottles.

Storage & Handling

Shelf Life
24 Months
Handling Precautions

Isododecane may cause skin irritation upon repeated and prolonged exposures. Proper dilution of this product into consumer personal care end products is recommended.

Usable Life and Storage

When stored at or below 32°C in the original unopened containers, this product has a usable life of 24 months from the date of production.

Disposal Considerations

Dispose in accordance with all local, state (provincial) and federal regulations. Empty containers may contain hazardous residues. This material and its container must be disposed in a safe and legal manner.