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PEROXAN APO is tert-Amyl peroxy-2-ethylhexanoate 95%, Liquid.PEROXAN APO is used for the (co)polymerization of ethylene, styrene, acrylonitrile, acrylates and methacrylates.

Chemical Name: tert-Amyl peroxyneodecanoate

Functions: Curing Agent, Initiator

CAS Number: 68299-16-1

Chemical Family: Peroxides

Compatible Polymers & Resins: Acrylics, Polyethylenes (PE), Polystyrenes (PS)

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Knowde Enhanced TDS

Identification & Functionality

Chemical Family
Plastics & Elastomers Functions
CAS No.
68299-16-1
EC No.
269-597-5

Applications & Uses

Plastics & Elastomers End Uses
Recommended Applications

Polymerization of ethylene : PEROXAN APO is used for high pressure in both autoclave and tubular processes, usually in combination with other peroxides of varying degrees of activity. Temperature range: 160 to 210°C Light-off temperature at 2300 bar: 184°C

Polymerization of styrene: PEROXAN APO may be used in polymerization and copolymarization of styrene. Temperature range: 80 to 110°C Dosing: 0,1 to 0,5 phr

Polymerization of acrylates and methacrylates: PEROXAN APO can be used as initiator for the solution, bulk and suspension (co)polymerization of acrylates and methacrylates. Temperature range (solution polym.): 70 to 120°C Dosing: 0,1 to 1 phr

Other applications: PEROXAN APO may also be used for the (co)polymerization of acrylonitrile.

Properties

Physical Form
Appearance
Clear Liquid
Typical Properties
ValueUnitsTest Method / Conditions
Active oxygen assaymin. 6.6%
Density at 20°C0.9g/cm³
Molecular Weight230.4
Peroxide assaymin. 95%

Technical Details & Test Data

Half Life Information
t ½ 10 h 1 h 1 min
bei73°C 91°C 128°C

 

Major Decomposition Products
  • 3-(1,1-Dimethylpropoxy)heptane
  • Acetone
  • Ethane
  • Heptane
  • Carbon dioxide
  • Methane
  • tert Amyl-alcohol

Safety & Health

Safety Characteristics
SADT 35°C
Emergency temperature 25°C
Control temperature 20°C

 

Packaging & Availability

Packaging Information
  • 25kg container

Storage & Handling

Shelf Life
3 Months
Product Handling and Storage
  • Maximum storage temperature (Ts max) : 5°C
  • Storage stability as from date of delivery : 3 months
  • Organic Peroxides are more or less stable products but will decompose under the influence of heat. To minimize a loss of quality during storage, it is important that the recommended maximum storage temperature is not exceeded. If a minimum storage temperature is given, an undesirable process such as a solidification or phase separation, is known to occur below this temperature.
  • Please refer to the material safety data sheet (MSDS) for information concerning safe storage, use and handling of PEROXAN APO.