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PEROXAN PB is tert-Butyl peroxybenzoate 98%, Liquid.PEROXAN PB is used for the (co)polymerization of ethylene, styrene, acrylonitrile, vinylacetate, acrylates and methacrylates.PEROXAN PB is used for the curing of unsaturated polyester resins.PEROXAN PB is used for the crosslinking of natural rubber and synthetic rubber, as well as polyolefins.

Functions: Curing Agent, Initiator

Chemical Family: Peroxides

Compatible Polymers & Resins: Acrylics, Ethylene Propylene Diene Monomer (EPDM), Ethylene Vinyl Acetate (EVA), Low-Density Polyethylene (LDPE), Natural Rubbers (NR), Nitrile Butadiene Rubber (NBR), Polyethylenes (PE), Polystyrenes (PS), Styrene Butadiene Rubber (SBR), Unsaturated Polyester (UPE)

Processing Methods: Pultrusion

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Identification & Functionality

Chemical Family
Plastics & Elastomers Functions

Features & Benefits

Materials Features

Applications & Uses

Plastics & Elastomers End Uses
Plastics & Elastomers Processing Methods
Recommended Applications

Polymerization of ethylene : PEROXAN PB is used for high pressure in both autoclave and tubular processes, usually in combination with other peroxides of varying degrees of activity. Temperature range: 220 to 270°C Light-off temperature at 2300 bar: 225°C

Polymerization of styrene: PEROXAN PB may be used in polymerization and copolymarization of styrene. In a mass process PEROXAN PB can be used to increase polymerization rates. In suspension polymerization processes, PEROXAN PB is often used for reduction of residual styrene content during the final polymerization stage. Temperature range: 100 to 140°C Dosing: 0,02 to 0,1 phr

Polymerization of acrylates and methacrylates: PEROXAN PB can be used as initiator for the solution, bulk and suspension (co)polymerization of acrylates and methacrylates. Temperature range: 90 to 130°C Dosing: 0,1 to 1 phr

Other applications: PEROXAN PB may also be used for the (co)polymerization of acrylonitrile and vinyl acetate.

Properties

Physical Form
Insoluble in
Water
Soluble in
Phthalates
Typical Properties
ValueUnitsTest Method / Conditions
Active oxygen assaymin. 8.07%
Density at 20°C1.04g/cm³
Molecular Weight194.2
Peroxide assaymin. 98%

Regulatory & Compliance

Certifications & Compliance

Technical Details & Test Data

Half Life Information
t ½ 10 h 1 h 1 min
bei103°C 122°C 160°C

 

Major Decomposition Products
  • Acetone
  • Benzoic acid
  • Benzene
  • benzene
  • Carbon dioxide
  • tert-Butanol

Safety & Health

Safety Characteristics
Flash point >SADT°C
SADT 60°C

 

Packaging & Availability

Packaging Information
  • 25kg container

Storage & Handling

Shelf Life
6 Months
Product Handling and Storage
  • Maximum storage temperature (Ts max) : 30°C
  • Minimum storage temperature (Ts min) : 10°C
  • Storage stability as from date of delivery : 6 months
  • Keep packaging tightly closed in a well ventilated place at indicated storage temperature. Keep away from reducing agents e.g. amines, acids, alkalis, heavy metal compounds (e.g. accelerators, driers, metal soaps). Never weigh out in storage room. Oxidizing agent. Decomposes violently under the influence of heat or by contact with reducing agent. Never mix with accelerators. Organic Peroxides are more or less stable products but will decompose under the influence of heat. To minimize a loss of quality during storage, it is important that the recommended maximum storage temperature is not exceeded. If a minimum storage temperature is given, an undesirable process such as a solidification or phase separation, is known to occur below this temperature.
  • Please refer to the material safety data sheet (MSDS) for information concerning safe storage, use and handling of PEROXAN PB.