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PUREfos 168 is a hydrolytically stable phosphite processing stabilizer. It acts as a secondary antioxidant during plastic processing and protects the polymer matrix by reacting with the hydroperoxides formed at this stage by auto-oxidation. The combination of PUREfos 168 with primary antioxidants provides a synergistic stabilization activity, preventing the overall thermo-oxidative degradation of the material.

Functions: Secondary Antioxidant, Stabilizer

Compatible Polymers & Resins: Acrylonitrile Butadiene Styrene (ABS), Ethylene Vinyl Acetate (EVA), High-Density Polyethylene (HDPE), Linear Low Density Polyethylene (LLDPE) , Polyamides, Polybutadienes, Polybutylene Terephthalate (PBT), Polycarbonates (PC), Polyethylene Terephthalate (PET), Polypropylenes (PP), Polystyrenes (PS), Styrene Butadiene Styrene (SBS)

Features: Free Flowing, Good Color Stability, High Hydrolysis Resistance, High Hydrolytic Stability, High Temperature Strength, High Thermo-Oxidative Stability, Low Volatility

Synonyms: 2,4-Bis(1,1-dimethylethyl)phenol phosphite, Tri(2,4-di-t-butylphenyl) phosphite, Tri(2,4-di-tert-butylphenyl) phosphite, Tri(2,4-tert-butylphenyl) phosphite, Tris [2,4-di-tert-butylphenyl] phosphite, Tris(2,4-di-t-butylphenyl)phosphite, Tris(2,4-di-tert-butylphenoxy)phosphine, Tris(2,4-di-tert-butylphenyl) phosphite, Tris(2,4-di-tert-butyphenyl) phosphite, Tris(2,4-tert-butylphenyl) phosphite

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Identification & Functionality

Plastics & Elastomers Functions
CAS No.
31570-04-4
EC No.
250-709-6
Chemical name

Tris(2,4-ditert-butylphenyl) phosphite

CAS number

31570-04-4

Chemical Structure

Polygel PUREfos 168 Chemical Structure

Features & Benefits

Features & Benefits

PUREfos 168 is an organo-phosphite of low volatility and can be used at high processing temperature. It is particularly resistant to hydrolysis.

PUREfos 168 protects polymers that are prone to oxidation during pelletizing, compounding, converting, recycling, as well as any processing step exposing the matrix to oxygen, high temperature and mechanical stress. It prevents molecular weight changes in the material triggered by the degradation processes such as chain scission (dominant in case of PP) and cross linking (dominant in the case of LDPE). It also contributes to reduce discoloration effects such as yellowing or pinking. PUREfos 168 blend with other primary antioxidants (PUREstab 1010 and PUREstab 1076) has a very good synergetic effects for polymer stability.

Applications & Uses

Applications

PUREfos 168 is a hydrolytically stable phosphite processing stabilizer. As a secondary antioxidant, it protects the polymer, in particular during the early stages of the processing step where oxygen, high temperature and mechanical stress trigger the formation of hydro-peroxide species responsible for degradation. PUREfos 168 reacts with hydro-peroxides to yield non-radical harmless products and is therefore called hydro peroxide decomposer.

As a secondary antioxidant, PUREfos 168 can be combined with primary antioxidants such as PUREstab 1010 or PUREstab 1076 providing a synergistic blend for applications in polyolefins or olefin-copolymers such as HDPE, LLDPE, PP, EVA, as well as PC, PA. These types of blends can also be used in engineering plastics such as PBT, PET and styrenic elastomers like PS, ABS, BR, SBS as well as tackifier resins and adhesives.

Guidelines for Use

Recommended loading concentrations of PUREfos 168 range between 0.05% and 0.2% combined with appropriate levels of other additives required for a proper processing stabilization of polymers.

Properties

Color
Physical Form
Appearance
White free flowing powder
Soluble in
Water, Ethanol, Chloroform, Acetone, Methanol, Ethyl Acetate, Methylene Chloride, n-hexane
Physical Properties
ValueUnitsTest Method / Conditions
Melting Range181 - 186.5°C
Vapor Pressure7.0e-10Pa
Flash Pointmin. 297°C
Bulk Density480 - 630 g/l
Solubility
ValueUnitsTest Method / Conditions
Acetone (at 20°C)47.0g/100g
Ethyl Acetate (at 20°C)47.0g/100g
Methanol (at 20°C)0.9g/100g
Methylene Chloride (at 20°C)63.0g/100g
Chloroform (at 20°C)71.0g/100g
Ethanol (at 20°C)1.5g/100g
n-Hexane (at 20°C)0.3g/100g
Water (at 20°C)max. 0.01g/100g

Technical Details & Test Data

Molecular weight

646.9 g/mol

Safety & Health

Handling & Safety

In accordance with good industrial practice, handle with care and avoid unnecessary personal contact. Avoid continuous or repetitive breathing of dust. Use only with adequate ventilation. Avoid dust formation and ignition sources. For more detailed information please refer to the material safety data sheet.

Storage & Handling

Storage

This product may be stored up to two years in a sealed container. Containers should be kept tightly closed when not in use and stored in a cool, dry place.