CAS-20® 4 Calcium Sulfate Filler

1 of 2 products in this brand
Cas-20® 4 Calcium Sulfate Filler can be used at high loadings and consistently provides an excellent balance of properties and good surface appearance.

Chemical Family: Calcium Salts

Functions: Filler

Features: Acid Resistant, Excellent Dielectric Properties, Excellent Opacity, Good Balance of Properties, Good Brightness, Good Impact Strength, Good Processability, High Purity, Low Specific Gravity, UV Resistant

End Uses: Appliances

Synonyms: Basic calcium sulfate, Calcium sulfate (CaSO4), Calcium sulphate, Sulfuric acid calcium salt, Sulfuric acid calcium(2+) salt (1:1)

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Knowde Enhanced TDS

Identification & Functionality

Chemical Family
Chemical Name
Plastics & Elastomers Functions
CAS No.
7778-18-9
EC No.
231-900-3

Features & Benefits

Features
  • High purity, whiteness
  • Soft, low abrasion
  • Resistance to weak acids
  • Improved UV resistance
  • Excellent impact properties
  • Good processibility
  • Excellent Dielectric properties
  • Lower specific gravity than barium sulfate
  • Resistance to mild acids
  • Good electrical properties
  • Cost savings potential

Applications & Uses

Plastics & Elastomers End Uses
Applications

CAS-20-4 filler is ideal for many rigid PVC applications, including:

  • Vinyl siding
  • Window frames
  • Moldings
  • Conduit
  • Pipe

Properties

Typical Properties
ValueUnitsTest Method / Conditions
Specific Gravity3--
pH-10% Slurry10.8--
Mohs Hardness2-3--
Refractive Index1.6--
Dielectric Constant5.6--
Oil Absorption24-26--
Loose Bulk Density45lbs./ft.3-
Packed Bulk Density65lbs./ft.3-
L95.4--
a0.5--
b1.9--
Median Particle Size4.6microns-
Top Particle Size26microns-
Calcium Sulphate (CaSO4)98.7--
CaCO3.MgCO30.5--
Calcium Carbonate (CaCO3)0.3--
Aggregate0.3--
Free Moisture at 113 °F (45 °C)0.1--
Combined Moisture at 437 °F (225 °C)0.2--
Blaine Surface Area10000-14000cm2/g-

Regulatory & Compliance

Regulatory Information
Country Standard Information
USA FDA Title 21, Volume 3, Part 184 Anhydrous Calcium Sulfate is recognized as Generally Recognized As Safe (GRAS).
Europe EU 10/2011 Anhydrous Calcium Sulfate is included in Article 6, section 3(a) (Page 16) as a Calcium Salt of Sulphuric Acid, which is listed as an authorized acid under FCM substance number 511 in ANNEX I (page 68).
China China GB 9685 Anhydrous Calcium Sulfate (CAS 7778-18-9) is listed as an acceptable additive on page 172 of standard.
France French Positive List Calcium Sulfate is allowed and listed under the Group C minerals section (page 240) of the French Positive List (Circulaire No 176 of 2 December 1959 and amendments).

 

Technical Details & Test Data

Typical Particle Size Data
Microtrac Analysis % Passing
26 microns 100.0
11 microns 94.0
5.5 microns 68.0
4.62 microns (median) 58.0
1.945 microns 14.0
0.972 micron 3.0

 

Product Comparison

TEST 1

Capstock tests indicate that calcium sulfate can provide equivalent or better properties than higher priced calcium carbonates.This test was conducted on four vinyl siding capstock formulations. #1 and #2 contained calcium carbonate and #3 and #4 contained calcium sulfate (CAS-20-4). All other additives were held constant. Dry blends were prepared by Vista Chemical. 7"*45 mil profiles were processed by a major vinyl siding manufacturer on a 40 mm American Maplan twin-screw extruder. Formulations and test results were as follows.

Brand Name 10 phr CaCO3 #1 15 phr CaCO3 #2 10 phr CaSO4 #3 15 phr CaSO4 #4 Function Composition Supplier
Vista 5385 100 100 100 100 PVC resin 0.92 IV homopolymer Vista Chemical
TM181 1.5 1.5 1.5 1.5 Thermal stabilizer Tin mercaptide Morton International
Extra-Dense G 1.2 1.2 1.2 1.2 Lubricant Calcium stearate Witco Corp.
Rheolub 165-010 1.2 1.2 1.2 1.2 Lubricant Paraffin wax Rheochem Mfg. Co.
AC629A 0.2 0.2 0.2 0.2 Lubricant Polyethylene wax Allied Signal Inc.
K12ON 1 1 1 1 Processing aid Acrylic copolymer Rohm & Haas Co.
KM334 6 6 6 6 Impact modifier Acrylic copolymer Rohm & Haas Co.
Omyacarb® UFT 10 15 - - Filler Calcium carbonate Omya Inc.
CAS-20-4 - - 10 15 Filler Calcium sulfate U.S. Gypsum Co.
CR834 10 10 10 10 White pigment Titanium dioxide Kerr McGee

RESULTS

ASTM D638 10 phr CaCO3 #1 15 phr CaCO3 #2 10 phr CaSO4 #3 15 phr CaSO4 #4
Tensile Strength at Yield, psi 6,390 6,180 6,270 6,070
Tensile Strength at Yield, kPa 44,060 42,610 43,230 41,850
Tensile Modulus * 10^5, psi 4.35 4.89 3.81 4.46
Tensile Modulus * 10^6, kPa 3.00 3.37 2.62 3.07
Elongation at Yield, % 2.9 3.0 3.4 3.0
ASTM D3029 10 phr CaCO3 #1 15 phr CaCO3 #2 10 phr CaSO4 #3 15 phr CaSO4 #4
Falling Weight Impact, in.-lb. 87.0 75.2 102.7 71.2
Falling Weight Impact, J 9.8 8.5 11.6 8.0

Capstock tests indicate that calcium sulfate can provide equivalent or better properties than calcium carbonate.

TEST 2

This independent study was conducted on two typical vinyl siding substrate formulations, one containing 8 phr of calcium carbonate and one containing 8 phr of calcium sulfate (CAS-20-4). Dry blends were prepared on site by a vinyl siding manufacturer. All other additives were held constant. Profiles, measuring 7"*40 mil, were processed on a 40 mm American Maplan twin-screw extruder.

ASTM D638 8 phr CaCO3 (OMYACARB® UFT) #1 8 phr CaSO4 (CAS-20-4) #2
Tensile strength at yield, psi 6,750 6,810
Tensile strength at yield, kPa 46,540 46,950
Tensile modulus * 10^5, psi 3.45 4.46
Tensile modulus * 10^6 , kPa 2.38 3.07
Elongation at yield, % 3.9 3.8
ASTM D3029 8 phr CaCO3 (OMYACARB® UFT) #1 8 phr CaSO4 (CAS-20-4) #2
Falling Weight Impact, in.-lb. 102.7 100.0
Falling Weight Impact, J 11.6 11.3

Substrate tests demonstrate that, at comparable loading levels, CAS-20-4 can provide significantly higher modulus and equivalent impact strength versus ultrafine treated carbonate.

Particle Size Distribution
Volume (Microtrac) Cumulative % Passing Weight (Sedigraph) % Smaller Than
20 microns 100.0 20 microns 100.0
10 microns 87.0 10 microns 92.3
5 microns 55.5 5 microns 68.4
4.3 microns (median) 50.0 3.5 microns (median) 50.0
2 microns 22.0 2 microns 30.1
1 micron 8.9 1 micron 4.1

 

Packaging & Availability

Packaging Type

Storage & Handling

Storage & Use

When properly used, USG CAS-20-4 Anhydrous Calcium Sulfate Filler is easy to work with. Keep indoors at temperatures between 65 °F – 75 °F (18 °C – 24 °C) and 45% – 55% RH. Do not stack more than two pallets high. Keep from drafts. Rotate stock. USG CAS-20-4 Anhydrous Calcium Sulfate Filler should be used within one year of the manufacturing date located on the package. Always follow handling and use directions and safety warnings on the package.