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Citrus Terpenes (Orange d-Limonene)

Evera's Citrus Terpenes, is a technical grade, colorless citrus ingredient which is rich in d-Limonene with some moderate orange notes. It can be used in several industries such as: Chemical Industry: paint, tire, solvents Pharmaceuticals: cannabidol, natural antibiotics (carvacrol) Natural insecticides and herbicides Flavor and fragrances (natural mentol) Cosmetics and homecare. Citrus terpenes are extracted during the secondary side stream valorization of the orange peel, seeds, rags.

INCI Name: Limonene

Chemical Name: (R)-p-mentha-1,8-diene, Citrus Aurantium Dulcis (Orange) Flower Extract, Limonene

Functions: Animal Repellent, Anti-Microbial Agent, Flavoring Agent, Fragrance, Herbicide, Insecticide, Paint Remover, Solvent, Stripping Agent

Chemical Family: Terpenes

Grade: Technical Grade

Knowde Enhanced TDS

Identification & Functionality

Chemical Family
Flavor Family
Fragrance
Fragrance Family
Fragrance Ingredient Class
INCI Name
Cleaning Ingredients Functions
Cosmetic Ingredients Functions
Food Ingredients Functions
Product Details
Botanical Specie

Citrus sinensis (L.) Osbeck

Variety A blend of major Brazilian varieties. Hamlin,
Pera Rio, Valencia and Natal
Color Colorless to pale yellow
Season of crop (Harvesting period)

May to December

Region Brazilian Citrus Belt
Key GC molecules a-pinene, sabinene, myrcene, octanal, limonene, decanal and linalool
Technology Citrus terpenes distilled from orange peel and pomace press liquor emulsion

Features & Benefits

Benefit Claims
Key Benefits
  • Citrus ingredient ​of multiple usage, source of d-Limonene, distilled raw-material to use in chemical industry
  • Safe for use in food, drinks or other consumer products
  • Neutral taste
  • Good solvency power
  • Plant based
Health Benefits
  • Reducing oxidative stress
  • Reducing the risk of diabetes
  • Reducing the risk of cancer
  • Reducing inflammation
  • Protecting the heart
  • Protecting the gastrointestinal system
  • Protecting the liver
  • Regulating the immune system
d-Limonene as Natural Insecticide and Herbicide

Benefits of insecticide that contains Terpene:

  • Biodegradable
  • Friendly to the Environment
  • Breaks surface tension
  • Desiccant effect on bugs
  • Large volumes available
  • Non-toxic to workers
  • Marketing appealing
  • Active ingredient effect
  • Adjuvant effect
  • Penetrates on the plant layer
  • Mix well with other products
  • Smells good
  • Multi-application
  • Already being commercialized
Product Highlights
  • D limonene ((R) limonene) is one of the monoterpenes most commonly found in plants The D limonene content is particularly high in many citrus peel oils and the main component of orange oil.
  • As the main fragrance of citrus peels, D limonene is used in food manufacturing and some medicines, such as a flavoring to mask the bitter taste of alkaloids, and as a fragrance in perfumery, aftershave lotions, bath products, and other personal care products. D Limonene is also used as a botanical insecticide.
  • D limonene is a chemical compound that naturally occurs in the peel of citrus fruits, such as oranges or lemons. It belongs to a family of chemicals known as terpenes . People can purchase d limonene as a dietary supplement. Companies also use it to give foods and beverages a citrus flavor
  • Limonene is a naturally occurring chemical which is used in many food products, soaps and perfumes for its lemon like flavor and odor. Limonene also is a registered active ingredient in 15 pesticide products used as insecticides, insect repellents, and dog and cat repellents.
  • Pesticide products containing limonene are used for flea and tick control on pets, as an insecticide spray, an outdoor dog and cat repellent, a fly repellent tablecloth, a mosquito larvicide, and an insect repellent for use on humans.
  • Formulations include ready to use solutions, emulsifiable concentrates, granular and impregnated material. Limonene is applied by hand as needed, both indoors and outdoors.
  • Use practice limitations include a label prohibition against use on weanling kittens and a caution against use of undiluted product.
  • Limonene is common as a dietary supplement and as a fragrance ingredient for cosmetics products As the main fragrance of citrus peels, D limonene is used in food manufacturing and some medicines, such as a flavoring to mask the bitter taste of alkaloids , and as a fragrance in perfumery , aftershave lotions, bath products, and other personal care products
  • D Limonene is also used as a botanical insecticide D Limonene is used in the organic herbicide, Avenger .It is added to cleaning products, such as hand cleansers to give a lemon or orange fragrance (see orange oil ) and for its ability to dissolve oils .In contrast, L limonene has a piny turpentine like odor.
  • Limonene is used as a solvent for cleaning purposes, such as adhesive remover , or the removal of oil from machine parts, as it is produced from a renewable source (citrus essential oil, as a byproduct of orange juice manufacture ). It is used as a paint stripper and is also useful as a fragrant alternative to turpentine. Limonene is also used as a solvent in some model airplane glues and as a constituent in some paints. Commercial air fresheners, with air propellants, containing limonene are used by stamp collectors to remove self adhesive postage stamps from envelope paper
  • Limonene is also used as a solvent for fused filament fabrication based 3D printing Printers can print the plastic of choice for the model, but erect supports and binders from High Impact Polystyrene (HIPS), a polystyrene plastic that is easily soluble in limonene.
  • In preparing tissues for histology or histopathology, D limonene is often used as a less toxic substitute for xylene when clearing dehydrated specimens. Clearing agents are liquids miscible with alcohols (such as ethanol or isopropanol ) and with melted paraffin wax , in which specimens are embedded to facilitate cutting of thin sections for microscopy It is also combustible and has been considered as a biofuel
  • Valencene is a sesquiterpene that gets its name from the place it’s most commonly found in Valencia oranges. Its citrusy, sweet aromas and flavors can be reminiscent of oranges, grapefruits, tangerines, and occasionally of fresh herbs or freshly cut wood.
  • The fragrant terpene is responsible for familiar citrus aromas frequently found in a wide variety of cannabis strains. It is also a known repellent of ticks and mosquitos.
  • The potential medical benefits of valencene are still being researched, but there is evidence that it may produce the following effects:
    • Anti inflammatory
    • Insectifugal
  • Cannabis strains that can test relatively high in valencene include such citrus forward strains as Tangie and Agent Orange

Applications & Uses

Bath & Shower Applications
Fragrances & Perfume Applications
Personal Hygiene Applications
Skin Care Applications

Properties

Physical Form
Odor
Strong citrus odor
Appearance
Clear liquid
Specifications
ValueUnitsTest Method / Conditions
Aldehyde Content0.20 - 1.20%USP
Specific Weight (at 25/25°C)0.839 - 0.850EOA Densimeter
Limonene Content92 - 96Area %GC-FID
Refractive Index (at 20˚C)1.4700 - 1.4750EOA Refractometer

Regulatory & Compliance

Technical Details & Test Data

Working Procedure
  • D Limonene is a fragrance, degreaser and gentle but powerful cleaner that is considered effective in removing stains, grease, tar and other substances and is a natural replacement for the more common solvents that typically contain chlorine or oil.
  • Because of its softness, it has become a popular ingredient in waterless hand soaps, which say it not only cleans but also leaves hands fresh. When applied to various types of hard surfaces such as boards, windows, mirrors, floors, bathtubs, refrigerators, automobiles, and electronics, d Limonene is considered a polisher.
Global Availability of d Limonene & Terpene
  • The global annual production of d-Limonene (Citrus Terpene technical grade) is roughly 30 ktons .
  • Brazil is the largest producer of d-Limonene and accounts for about 70% global share.
  • When orange oils is concentrated (folded), Orange Terpene is produced.
  • It is estimated that 25 ktons of Orange Terpene (food grade) is produced annually.
  • Total availability of d-Limonene (Citrus Terpene) and Orange Terpene is around 55 ktons


Estimated Global Production of d Limonene, Technical Grade (Ktons) 

Citrus Terpenes (Orange d-Limonene) - Global Availability of D Limonene & Terpene


Utilization of 50Ktons of Orange Oil

Citrus Terpenes (Orange d-Limonene) - Global Availability of D Limonene & Terpene - 1

Application Example
  • Desiccant effect on bugs
  • Kills on contact


Citrus Terpenes (Orange d-Limonene) - Application Example 

Packaging & Availability

Packaging Type
Packaging Information
  • For Drums: Steel drum with fixed cover and 02 tamper evident seals.
  • Net Weight: 173 ± 1.5Kg per drum.
  • For Bulk: Stainless steel container.
  • Other packaging sizes available upon request.

Storage & Handling

Shelf Life
24 Months
Storage Information
  • For drums: The drums must be stored at room temperature and protected from direct sunlight and excessive heat.
  • For bulk: In room temperature protected from direct sunlight and excessive heat.
  • Shelf Life: 24 months, provided the storage conditions have been respected.