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Marathwada Chemicals Zinc Phosphate

Marathwada Chemicals Zinc Phosphate is a valuable corrosion resistent Pigment and we are happy to introduce it as an addition to our existing products ALUMINA HYDRATE and GLOSS WHITE. ZINC PHOSPHATE is in more use in the West.

Chemical Name: Zinc Phosphate

CAS Number: 7779-90-0

Labeling Claims: Non-Toxic

Synonyms: Zinc(II) Phosphate

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    Identification & Functionality

    CI Number
    Chemical Name
    Base Chemicals Functions
    CAS No.
    7779-90-0
    Chemical Formula
    Zn3(PO4)2.2H2O
    EC No.
    231-944-3
    Chemical Nature

    This Pigment is essentially Zinc Phosphate Dihydrate and corresponds to the formula Zn3(PO4)2.2H2O. It is a white, non toxic Pigment and is prepared by precipitation.

    Features & Benefits

    Labeling Claims
    Features
    • Color: Zinc Phosphate is white in appearance and of low opacity, making it adaptable to wide range of colors, by incorporating other pigments.
    • Non-toxicity: Both red lead and calcium plumbate pigments are toxic. this not only limits their usage, but means that they can only be sprayed with elaborate precautions. Primers containing Zinc Phosphate are not toxic.
    • Performance: Standard corrosion control tests can be misleading when evaluating the performance of Zinc Phosphate-based Primers. The Girder Test and performance are more reliable guides.
    Advantages
    • Zinc Phosphate has the advantage of bright white color and non toxic nature over other Corrosion Resistant Pigments much as Zinc Chromate, Zinc Tetroxy Chromate and Barium Chromate.
    • The use of Zinc Phosphate in Primers promotes excellent inter-coat adhesion, particularly under conditions of high humidity.

    Applications & Uses

    Applications
    • It is compatible with a vide variety of media including alkyds epoxy esters, chlorinated rubber, polyurethene etc. Though the exact mechanism is not thoroughly understood, it is probable that, due to its slight solubility Zinc Phosphate reacts by polarizing both anodic and cathodic areas. The Pigment also physically prevents passage of water and salts. Thus the corrosion resistance characteristics of Zinc Phosphate Pigment factors.
    • Zinc Phosphate is used in corrosion resisting primers and undercoats.Good brushing characteristics can be obtained with Zinc Phosphate Primers, which are suitable for both airless and conventional spray application. None of these methods entails a health hazard.
    • In contrast with the majority of red lead primers which are formulated in slow drying oils, it is now possible to formulate a 2-hour overcoatable paint based on Zinc Phosphate, without detriment to its anti-corrosive properties.

    Properties

    Physical Form
    Appearance
    White, Micro-Crystallian Powder
    Typical Properties
    ValueUnitsTest Method / Conditions
    Residue on Sieve of 240 Meshmax. 0.5%-
    Specific Gravity3.3--
    Bulk Density0.6-0.9G/ML-
    Oil Absorption19±2Per 100g-
    Loss on Ignition (Mass)8.5 - 10%
    Matter soluble in watermax. 0.5%-
    Zinc Content of Ignited Sample (Mass)50.5 - 52.0%

    Technical Details & Test Data

    Mechanism Of Corrosion Protection

    A number of explanations have been put forward about the effectiveness of Zinc Phosphate in inhibiting rust formation. Among these are suggestions that it reduces the diffusion rate of ammonium ions through paint film, that it slowly “phosphates” the metal surface, rendering it passive, or that, as a result of complex formation between Zinc Phosphate and the media, a highly stable film is produced.