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Acrylic Bead Resins TB-322

1 of 3 products in this brand
Acrylic Bead Resins TB-322 is a solid bead methacrylate copolymer intended for use in solvent-based coating systems where improved adhesion to difficult metals is important. TB-322 exhibits excellent outdoor durability. The resin may be used in adhesives and a variety of metal coatings applications such as transportation finishes in automotive, container and other marine coatings, and a variety of brass and aluminum coating applications.   *Acrylic Bead Resins is provided by Mitsubishi Chemical Corporation, a member of the Mitsubishi Chemical Group.

Chemical Family: Methacrylates

End Uses: Solventborne Coating

Compatible Substrates & Surfaces: Aluminum, Brass, Copper, Metal, Steel, Tin, Zinc

Features: Improves Adhesion, Outdoor Durability

Knowde Enhanced TDS

Identification & Functionality

Chemical Family
CASE Ingredients Functions
Technologies

Features & Benefits

CASE Ingredients Features

Applications & Uses

Compatible Substrates & Surfaces

Properties

Physical Form
Appearance
Solid bead
Soluble in
Toluene, Methyl Ethyl Ketone (30% in Solvent), Acetone (30% in Solvent), Ethyl Acetate (30% in Solvent), Dimethyl Carbonate (30% in Solvent), t-Butyl Acetate (30% in Solvent), n-Butyl Acetate (30% in Solvent), Parachlorobenzotrifluoride (30% in Solvent)
Insoluble in
Isopropyl Alcohol (30% in Solvent), Methanol (30% in Solvent), Mineral Spirits (30% in Solvent), Water (30% in Solvent)
Typical Properties
ValueUnitsTest Method / Conditions
Glass Transition Temperature (Onset, Calculated)48.0°C
Molecular Weight60000.0
Acid Number3.4mg KOH/g Resin
Note

Typical physical properties listed are approximate values and should not be considered manufacturer’s release specifications. Manufacturer’s release specifications are subject to change without notice, please contact your representative for the latest product specification details.

UV Applications

Monomer

20% in Monomer
Dissolved with 10 min. heat at 65°C*

HDDA 400 cps
NPGDA 770 cps

*Viscosity was measured at 25°C

Technical Details & Test Data

Metal Adhesion Performance in Coatings
  Adhesion Performance1 Flexibility2
Cold-Rolled Steel 5 (excellent) Pass
Galvanized Steel 5 Pass
Aluminum 2024 5 Pass
Aluminum 5052 5 Pass
Zinc 5 Pass
Tin 5 Pass
Copper 5 Pass
Brass 5 Pass

Note:

  • Coatings was formulated at 40% solids in toluene without external plasticizer. The adhesion test was carried out after the film was dried at room temperature for one week.
  • 1Adhesion is rated on a 0 (poor, >65% coating area removed) to 5 (excellent, no failure) scale as described in ASTM D3359.
  • 2Flexibility is determined by the degree of cracking at a bend. The bend was performed after drying the coatings for one and four weeks at ambient temperature.
Technical Data

Adhesion on Metals (crosscut test per ASTM D3359)

Acrylic Beads Resins TB-322 - Technical Data

 

Strong adhesion on multiple substrates

Acrylic Beads Resins TB-322 - Technical Data - 1

Preparing Solutions

Our resins dissolve at room temperature but require constant agitation to prevent solvent-swollen granules of polymer from forming agglomerates and sticking to the walls of the vessel. Important: The polymer beads should be sifted directly into the vortex of the stirred solvent to speed wetting-out and dispersion. Continuous low-shear agitation for periods of 1-12 hours, depending on the grade and concentration of resin, is recommended.

After the solution appears clear in the tank, a sample should be spread out on a Leneta card or glass. After the solvent evaporates and a film forms on the card or glass, there should not be any resin seeds. If there are any seeds, the tank should be agitated further to fully dissolve the resin. Tank agitation should not be stopped (except for sampling) until the film test indicates there are no resin seeds. Any cloudiness or residue may indicate that some polymer remains undissolved. The presence of water in the system can also cause cloudiness.

Solution time can be reduced by heating; most common solvents can be heated to approximately 49°C (120°F) without the need for reflux equipment. High-shear agitation also cuts dissolving time, but requires care to avoid overheating and excessive solvent loss.