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Crestapol® 1211A Urethane Acrylate Resin

1 of 14 products in this brand
Crestapol® 1211A Urethane Acrylate Resin is a partially accelerated, filled, tough urethane acrylate resin designed for applications requiring the highest levels of fire and smoke performance. It incorporates a selected grade of alumina trihydrate (ATH), which makes it suitable for the production of laminates where excellent fire resistance and low levels of smoke and toxic fumes are required. This product is halogen-free and does not contain heavy metals.

Polymer Name: Urethane Acrylate

Chemical Family: Acrylics, Acrylates & Methacrylates, Urethanes

Processing Methods: Closed Molding, Pultrusion, Resin Transfer Molding (RTM), Vacuum Infusion Processing (VIP)

Technical Data Sheet

Knowde Enhanced TDS

Identification & Functionality

Additives Included
Polymer Name
Composite Materials Functions

Features & Benefits

Labeling Claims
Key Features
  • Low viscosity
  • Rapid cure
  • Excellent toughness
  • No post cure required
  • Pre-filled with a special grade of Alumina Trihydrate (ATH)
  • Excellent surface finish
  • Excellent FST performance
  • Crestapol® 1211A is a versatile resin with excellent fire, smoke & toxicity properties and good mechanical properties.
  • Its viscosity characteristics have been designed to promote a good resin flow through the mold using appropriate
  • reinforcements, whilst minimizing filler settlement during storage. It is recommended for use when excellent low smoke, low toxic fume emissions and fire resistant laminates is desired.

Applications & Uses

Applications

Crestapol® 1211A has been primarily designed for use in closed mold applications, including RTM and Vacuum infusion with suitable reinforcements. Due to its excellent fire, smoke & toxicity properties, the product can be used in the most demanding applications in the building and construction, public transport and railway industries.

Formulation Guidelines
Crestapol® 1211A is a pre-filled, partially accelerated resin and must be thoroughly stirred and allowed to attain workshop temperature (18°C - 23°C) before use. It requires the addition of a catalyst and one accelerator to start the curing reaction.
Recommended Applications
  • Catalyst and accelerators should not be mixed directly together, since they react with explosive violence. The recommended catalyst is MEKP (50%) and the recommended accelerator is Accelerator G (1% solution of cobalt, as cobalt octoate, in styrene monomer).
  • Cobalt free accelerators may be also considered (for more details on liquid cobalt free cure systems please seek assistance from our Technical Services Department). The accelerator should be added into the resin and thoroughly dispersed prior the injection of the resin in the RTM mold cavity. Catalyst Acetylacetone peroxide can also be used when faster demould times is required.
  • Dibenzoyl peroxide based catalysts can also be used to start the curing reaction without the need to add an accelerator. The recommended catalyst is Dibenzoyl peroxide (50%) and should be added into the resin at a level of 1.0% and thoroughly dispersed. The geltimes that can be achieved depend on the levels of accelerator and catalyst. Examples of approximate pot life are shown in the tables below.

Properties

Appearance
Cream
Resin Properties - (without post cure)
ValueUnitsTest Method / Conditions
Barcol Hardness45 - 50
Deflection Temperature Under Load (1.80MPa)64°C
Water Absorption (24 hours at 23°C)15 - 20mg
Tensile Strength32MPa
Tensile Modulus8GPa
Elongation (at Break)0.82%
Laminate Properties - (without post cure)
ValueUnitsTest Method / Conditions
Glass Content*15%
Tensile Strength*78MPa
Tensile Modulus*11.4GPa
Elongation (at Break)*1.35%
Flexural Modulus*9.4GPa
Flexural Strength*158MPa
Cured Properties
ValueUnitsTest Method / Conditions
Tensile Modulus7.9GPa
Tensile Strength33MPa
Barcol Hardness45 - 50
Deflection Temperature Under Load (1.80MPa) †77°C
Water Absorption (24 hours at 23°C)15 - 20mg
Elongation (at Break)0.89%
Uncured Properties
ValueUnitsTest Method / Conditions
Specific Gravity (at 25°C)1.54
Geltime*20 - 30minutes
Volatile Content22.3% wt./wt.
Geltime to Peak10minutes
Viscosity (at 25°C, 4500 s⁻¹)5Poise
Laminate Properties (Cured)
ValueUnitsTest Method / Conditions
Glass Content15%
Tensile Strength77MPa
Tensile Modulus10.1GPa
Elongation (at Break)1.48%
Flexural Strength141MPa
Flexural Modulus8.6GPa
Note
  • * Made with 4 layers 450g/m² PB CSM
  • ** Curing schedule at 24hrs at 20°C, 3hrs at 80°C
  • † Curing schedule at 24hours at 20°C, 5 hours at 80°C, 3 hours at 120°C
Pot Life

Table 1 – 1.5% MEKP (50%)

Parts of Accelerator G to 100
Parts of Catalyzed Resin
2.0 2.5 3.0
Pot life (mins) at 20ºC 26.1 21.7 22.7
Pot life (mins) at 25ºC 24.7 19.8 19.2

 

Table 2 – 1.5% Acetylacetone peroxide

Parts of Accelerator G to 100
Parts of Catalyzed Resin
2.0 2.5 3.0
Pot life (mins) at 20ºC 29.6 19.4 16.4
Pot life (mins) at 25ºC 24.3 16.9 13.4

Accelerator G = 1% cobalt as cobalt octoate in styrene monomer. 

 

Table 3 – Dibenzoyl peroxide (50%)

Parts of Perkadox® CH50-X 1.0 1.5 2.0
Pot life (mins) at 20ºC 29.5 23.8 17.0
Pot life (mins) at 25ºC 25.5 16.5 12.7

Inhibitor NLC-10 can be used at ambient temperature to lengthen the geltime of a mixture of Crestapol® 1211A/ Dibenzoyl peroxide (50%). The following table demonstrates the effect of Inhibitor NLC-10 addition to Crestapol® 1211A resin.

 

Inhibitor NLC-10 (on Resin) Typical Geltime (mins) at 20ºC
0.00% 25.5
0.05% 42.4
0.10% 60.9
0.15% 88.7

 

Technical Details & Test Data

Post Curing
Without post cure, laminates made with Crestapol® 1211A can reach approximately 90% of their total cure. Therefore, no post cure is required. For optimum fire retardant properties, however, laminates should be post cured before being put into service. The laminate should be allowed to cure for 24 hours at 20°C, and then be oven cured for 3 hours at 80°C.
Additives
Crestapol® 1211A is filled with a special grade of Alumina Trihydrate (ATH) to provide good resin flow in closed mold systems and also give excellent fire, smoke & toxicity properties. It incorporates anti-settling additives to minimize filler settlement during storage and promote good filler re dispersion in the resin.

Packaging & Availability

Country Availability
Packaging Type
Regional Availability
  • China
  • Europe
  • India
  • Middle East
  • Oceania
  • United Kingdom
Packaging
Crestapol® 1211A is supplied in 25kg and 300kg containers.

Storage & Handling

Shelf Life
3 Months
Storage
Crestapol® 1211A should be stored between 5°C and 25°C in the original, unopened container in a dry, well ventilated place. Protect from freezing and direct sunlight. Avoid contact with oxidizing agents. If stored outside of these recommendations, shelf life will be significantly reduced.