Knowde Enhanced TDS
Identification & Functionality
- Chemical Family
- Polymer Name
- Plastics & Elastomers Functions
- Technologies
Features & Benefits
- Labeling Claims
- Materials Features
Applications & Uses
- Applications
- Plastics & Elastomers End Uses
- Plastics & Elastomers Processing Methods
Properties
- Mechanical Properties
- Thermal Properties
- Other Properties
- Mechanical Properties (TPE)
- Rheological Properties
| Value | Units | Test Method / Conditions | |
| Yield Stress | 6 | MPa | ISO 527-1/-2 |
| Yield Strain | 50 | % | ISO 527-1/-2 |
| Nominal Strain at Break | >50 | % | ISO 527-1/-2 |
| Charpy Notched Impact Strength (at +23°C) | N | kJ/m² | ISO 179/1eA |
| Charpy Notched Impact Strength (at -30°C) | N | kJ/m² | ISO 179/1eA |
| Izod Notched Impact Strength (at +23°C) | N | kJ/m² | ISO 180/1A |
| Izod Notched Impact Strength (at -20°C) | N | kJ/m² | ISO 180/1A |
| Value | Units | Test Method / Conditions | |
| Melting Temperature (10°C/min) | 195 | °C | ISO 11357-1/-3 |
| Glass Transition Temperature (at 10°C/min) | -73 | °C | ISO 11357-1/-2 |
| Value | Units | Test Method / Conditions | |
| Density | 1110 | kg/m³ | ISO 1183 |
| Value | Units | Test Method / Conditions | |
| Tensile Modulus | 40 | MPa | ISO 527-1/-2 |
| Stress at 10% strain | 3 | MPa | ISO 527-1/-2 |
| Stress at 100% strain | 6.6 | MPa | ISO 527-1/-2 |
| Stress at Break | 20 | MPa | ISO 527-1/-2 |
| Strain at Break | >300 | % | ISO 527-1/-2 |
| Shore D Hardness (15s) | 33 | — | ISO 868 |
| Value | Units | Test Method / Conditions | |
| Melt Flow Index (at 230 / * °C, 2.16 / * kg) | 32 | g/10min | ISO 1133 |
| Molding Shrinkage (parallel) | 1.5 | % | Sim. to ISO 294-4 |
| Molding Shrinkage (normal) | 1.5 | % | Sim. to ISO 294-4 |
Regulatory & Compliance
- Certifications & Compliance
Technical Details & Test Data
- Chemical Resistance
Chemical Type Chemical Name Resistance Other Acetic acid (10% by mass) at 23°C resistant Ketones Acetone at 23°C resistant Other Ammonium hydroxide (10% by mass) at 23°C limited resistant, tests necessary to verify Other ASTM 1 at 23°C resistant Other ASTM 3 at 23°C resistant Other Brake fluids (DOT 3/4) at 23°C not resistant Other Calcium chloride (10% by mass) at 23°C limited resistant, tests necessary to verify Other Chloroform at 23°C not resistant Ethers Diethyl ether at 23°C limited resistant, tests necessary to verify Alcohols Ethanol at 23°C limited resistant, tests necessary to verify Other Ethyl Acetate at 23°C limited resistant, tests necessary to verify Other Fuel; Diesel at 85°C resistant Other Hydrochloric acid (10% by mass) at 23°C resistant Other Hydrogen peroxide (30% by mass) at 23°C limited resistant, tests necessary to verify Other Nitric acid (10% by mass) at 23°C resistant Other Phosphoric acid (10% by mass) at 23°C resistant Other Sodium hydroxide (10% by mass) at 23°C resistant Other Sulfuric acid (30% by mass) at 23°C resistant Other Tetrachloroethylene at 23°C limited resistant, tests necessary to verify Hydrocarbons Toluene at 23°C resistant Other Transformer oil at 23°C not resistant Other Trichloroethylene at 23°C not resistant Other Water at 23°C resistant Other Zinc chloride (10% by mass) at 23°C resistant - Machinery for Injection Molding
Arnitel® grades can be processed on general injection molding machines.
Screw Geometry- Typically 3-zone screw designs with volumetric compression ratios of approximately 2.5 work fine.
Steel Type
- Abrasive resistant tool steels which are normally used for glass and/or mineral reinforced materials are also to be used for Arnitel® polymers in tools, nozzles and screws.
Nozzle Temperature Control
- The use of an open nozzle with good temperature control and an independently-controlled thermocouple nearby the tip and heater bands with sufficient output is recommended.
Hot Runner Layout
- Try to achieve a close contact with your hot runner supplier and Envalior as the material supplier, to be sure that the right hot runner system is chosen.
- When processing Arnitel® with hot runners, keep in mind these basic rules:
- Central bushing heated separately
- Only use external heated system
- Manifold heated from both sides
- Tip with thermocouple in front (near gate)
- Very accurate temperature control in the gate area
- General Processing Settings For Injection Molding
Screw Rotation Speed
- To realize a good and homogeneous melt, it is advised to set a screw rotation speed resulting in a plasticizing time that is just within the cooling time.
- The rotational speed of the screw should not exceed 6500 / D RPM (where D is the screw diameter in mm).
Back Pressure
- Back pressure should be between 30-100 bars effective. Keep it low in order to prevent nozzle-drooling, excessive shear heating and long plasticizing times.
Decompression
- In order to prevent nozzle drool after plasticizing and retracting the nozzle from the mold, a short decompression stroke can be used. However, to prevent oxidation of the melt, which may result in surface defects on the parts, it is recommended to keep this as short as possible.
Injection Speed
- Moderate to high injection speeds are required in order to prevent premature crystallization in the mold during injection phase and to obtain a better surface finish. Adequate mold venting is required to avoid burning at the end of the flow path (due to diesel effect).
Injection Pressure
- The real injection pressure is the result of the flowability of the material (crystallization rate, flow length, wall thickness, filling speed). The set injection pressure should be high enough to maintain the set injection speed (use set injection pressure higher than the peak pressure if possible). Tooling air vents must be effective to allow optimum filling pressure and prevent burn marks.
Holding Time
- Effective holding time is determined by part thickness and gate size. Holding time should be maintained until a constant product weight is achieved.
Holding Pressure
- The most adequate holding pressure is the level whereby no sinkmarks or flash are visible. A too high holding pressure can lead to stresses in the part.
Cooling Time
- Actual cooling time will depend on part geometry and dimensional quality requirements as well as the tool design (gate size).
Ejection of The Part
- In view of Arnitel®'s flexibility (particularly the softer types) specific attention has to be given to the mold release. Furthermore the surface of the ejection pins should be large enough to prevent damage or deformation of the part.
- Temperature Settings For Injection Molding
Mold Temperature
- Arnitel® can be used with a wide range of tool temperatures (20 - 50°C / 68 - 122°F). However, to achieve optimal mechanical properties and stable dimensional parts, it is recommended to apply a tooling temperature at the higher side (50°C / 122°F).
- In case the molded part tends to stick to the mold, a lower mold temperature can contribute to a better part release.
Barrel Temperature
- The given temperature settings are general for Arnitel®. Optimal settings are governed by barrel size and residence time.
- Additionally, a higher hardness and higher melting point of the Arnitel®, requires a barrel temperature at the higher side.
Mold/Tool Measured melt Nozzle Front Center Rear 20-50°C
68-122°F220-240°C
428-464°F220-240°C
428-464°F210-230°C
410-446°F200-220°C
392-428°F190-210°C
374.-410°FMelt Temperature
- To generate a good and homogeneous melt, the melt temperature should always be above 220°C / 428°F. Optimal mechanical properties will be achieved at melt temperatures between 220-240°C / 428-464°F.
- We advise to frequently measure the melt temperature by pouring the melt in a Teflon cup and inserting a thermo probe into the melt.
Hot Runner Temperature
- A hot runner temperature set to the same level as the nozzle temperature should work fine and not lead to excessive overheat of the Arnitel® grade. When starting up, an increased tip temperature may be necessary to overcome a frozen nozzle.
- Melt Residence Time For Injection Molding
The optimal Melt Residence Time (MRT) for Arnitel® EM400-08 is ≤ 5 minutes with preferably at least 50% of the maximal shot volume used. The MRT should not exceed 6 minutes.
A formula to estimate the MRT is described below:
𝑀𝑅𝑇 = (∏D³ρ/m) * (t/60)
Whereas:
MRT = Melt Residence Time [minutes]
D = Screw Diameter [cm]
p = Melt Density [g/cm3)
m = Shot Weight [g]
t = Cycle Time [s]
Please note: In the calculation above, the hotrunner volume has not been taken into account. When a hotrunner is part of the setup, please add the hotrunner volume to the calculation.- Startup/Shut Down/Cleaning For Injection Molding
- Production has to be started and stopped with a clean machine. Cleaning can be done with Arnitel® EM400-08, applicable cleaning agents or HDPE. Hot runners can also be cleaned and put out of production cleaning them with Arnitel® EM400-08.
- Production Breaks For Injection Molding
- During production breaks longer than a few minutes, we advise emptying the barrel. The temperature of the barrel and the hot runner [if applicable) should be reduced to a level far enough below the melting point of the compound in order to stop decomposition of the compound.
- When the hot runner, nozzle, or even the screw is blocked, be aware that under these conditions a sudden outburst of molten material can take place. Always wear personal safety protections for hand/eye/body.
Packaging & Availability
- Packaging Type
Storage & Handling
- Material Handling For Injection Molding
Storage
- In order to prevent moisture pick up and contamination, supplied packaging should be kept closed and undamaged. For the same reason, partial bags should be sealed before re-storage.
- Allow the material that has been stored elsewhere to adapt to the temperature in the processing room while keeping the bag closed.
Packaging
- Arnitel® grades are supplied in airtight, moisture-proof packaging.
Moisture Content as Delivered
- Arnitel® grades are packaged at a moisture level ≤ 0.05 w%.
Conditioning Before Molding
- To prevent moisture condensing on granules, bring cold granules up to ambient temperature in the molding shop while keeping the packaging closed.
Moisture Content Before Molding
- Arnitel® is delivered at molding moisture specification (≤ 0.05 w%). We advise to pre-dry to overcome the fluctuation from package to package (see drying section below). Furthermore, pre-drying is required in case the material is exposed to moisture before molding (prolonged storage or open/damaged packaging).Moisture content can be checked by water evaporation methods or manometric methods (ISO 15512).
Drying
- Arnitel® grades are hygroscopic and absorb moisture from the air relatively quickly. Moisture absorption is fully reversible under the following drying conditions without compromising material quality. Preferred driers are dehumidified driers with dew points maintained between -30 and -40°C / -22 and -40°F. Vacuum driers with N₂ purge can also be used. Hot air ovens or hopper driers are not suitable for pre-drying Arnitel® grades; the use of such driers may result in non-optimum performance.
Moisture content Time Temperature [%] [h] [°c] [°F] <0.05
and as delivered3-4 100 212 >0.05-0.2 4-6 100 212 Regrind
- Regrind can be used taking into account that this regrind must be clean/low dust content/not thermally degraded/dry, of same composition and similar particle size as the original material. The acceptable level of regrind depends on the application requirements (e.g. UL Yellow Card). Be aware that regrind can cause some small color deviations.