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ULTEM™ Resin 4002

1 of 142 products in this brand
ULTEM™ Resin 4002 is a PTFE filled, standard flow Polyetherimide (Tg 217C). ECO Conforming, UL 94 V0 and 5VA listing in recognized colors.

Polymer Name: Polyether Imide (PEI)

Processing Methods: Injection Molding

Fillers Included: PTFE

Additives Included: Flame Retardant, Lubricant (Unspecified)

Flexural Modulus: 3100.0 - 3100.0 MPa

Technical Data Sheet

Knowde Enhanced TDS

Identification & Functionality

Fillers Included
Plastics & Elastomers Functions
Technologies

Features & Benefits

Ultem Resin Attributes for Eyewear Frames
  • Super tough
  • Meets JIS B7285, includes 20,000 cycles blending repetitions
  • Long life cycle
  • UV stabilized
  • Light weight
  • Excellent in chemical and hydrolytic resistance
  • Excellent dimensional stability
  • Thin wall molding down to 1.2 mm
  • Long term heat resistance (RTI > 170°C)
  • Available in custom colors

ULTEM resin delivers a broad range of desirable performance properties for eyeglass frames and is also potentially usable in safety and 3D eyewear frames.

 

Dimensional and Hydrolytic Stability

  • Ensures the lenses are retained in the frame
  • Extends the product life cycle

 

Temperature and Chemical Resistance

  • Excellent stain and chemical resistance
  • High heat deflection temperature protects the frames even when left on the car dashboard in direct sunlight

 

Design Freedom & Ease of Production

  • Precision thin wall molding at 1.2 mm
  • Capability for custom colors providing a wide range of esthetic effects
  • Enhanced processing window vs. nylons

 

Density

  • Intrinsically lightweight (up to 50% vs. metal)

 

Mechanical Properties

  • Higher flexural modulus at 3510MPa
  • Offers elasticity coupled with resistance to deformation, allowing the frame to bend easily yet return to its original shape
ULTEM™ Resin Offers
  • Lead times of approximately 4 weeks*
  • Up to 55% higher stiffness
  • Better dimensional stability vs. PSU
  • Excellent property retention at elevated temps:

Tg - 217°C, HDT @ 1.80 MPa: 190°C

  • Up to 17% lower CTE than PES/PPSU 
  • Chemical resistance
  • Metal plating compatibility
  • Compatibility with multiple sterilization methods
  • Availability for stock shapes & films
Product Highlight

The ULTEM™ family of amorphous thermoplastic polyetherimide (PEI) resins offer outstanding elevated thermal resistance, high strength and stiffness, and broad chemical resistance. ULTEM™ copolymers are also available for even higher heat, chemical and elasticity needs.

ULTEM™ resins uniquely balance both mechanical properties and processability, offering design engineers exceptional flexibility and freedom. ULTEM™ resins are also inherently flame retardant and possess excellent dielectric character. ULTEM™ resins are therefore an excellent candidate for your electric vehicle battery needs where high heat resistance is required.

With its appreciable flow and dimensional stability, coupled with excellent resistance to Li-ion electrolyte, ULTEM™ resins such as ULTEM™ CRS5011 resin are today being used for insulation of Li-ion cell terminals. Given its excellent dielectric character, ULTEM™ resin is also an ideal candidate for bus bar insulation. For other powertrain elements, such as DC power converters. ULTEM™ UTF120 dielectric film is already enabling high temperature film capacitors. 

 

Applications & Uses

Plastics & Elastomers Processing Methods

Properties

Flame Rating
Mechanical Properties
ValueUnitsTest Method / Conditions
Tensile Stress (Yield, Type I, 5 mm/min)105MPaASTM D638
Tensile Stress (Break, Type I, 5 mm/min)85MPaASTM D638
Tensile Strain (Yield, Type I, 5 mm/min)5%ASTM D638
Tensile Strain (Break, Type I, 5 mm/min)40%ASTM D638
Tensile Modulus (at 5 mm/min)3460MPaASTM D638
Flexural Stress (Yield, 1.3 mm/min, 50 mm span)155MPaASTM D790
Flexural Modulus (at 1.3 mm/min, 50 mm span)3550MPaASTM D790
Tensile Stress (Yield, 50 mm/min)100MPaISO 527
Tensile Stress (Break, 50 mm/min)80MPaISO 527
Tensile Strain (Yield, 50 mm/min)6%ISO 527
Tensile Strain (Break, 50 mm/min)25%ISO 527
Tensile Modulus (at 1 mm/min)3300MPaISO 527
Flexural Stress (Yield, at 2 mm/min)130MPaISO 178
Flexural Modulus (at 2 mm/min)3100MPaISO 178
Physical Properties
ValueUnitsTest Method / Conditions
Mold Shrinkage (on Tensile Bar, flow)0.6 - 0.8%SABIC method
Density1.33g/cm³ISO 1183
Mold Shrinkage (flow, 3.2 mm)0.5 - 0.7%SABIC method
Mold Shrinkage (xflow, 3.2 mm)0.5 - 0.7%SABIC method
Melt Flow Rate (at 337°C, 6.6 kgf)9.5g/10 minASTM D1238
Water Absorption (at 23°C, saturated)1.1%ISO 62-1
Specific Gravity1.33ASTM D792
Moisture Absorption (at 23°C, 50% RH)0.6%ISO 62
Melt Volume Rate (at 360°C, 5.0 kg)13cm³/10 minISO 1133
Thermal Properties
ValueUnitsTest Method / Conditions
Vicat Softening Temperature (Rate B/50)219°CASTM D1525
Vicat Softening Temperature (Rate B/50)215°CISO 306
Heat Deflection Temperature (at 1.82 MPa, 3.2mm, Unannealed)197°CASTM D648
Heat Deflection Temperature (at 1.82 MPa, 6.4 mm, Unannealed)200°CASTM D648
Coefficient of Thermal Expansion (at -40°C to 150°C, flow)0.0000391/°CASTM E831
Coefficient of Thermal Expansion (at -40°C to 150°C, xflow)0.000041/°CASTM E831
Coefficient of Thermal Expansion (at 23°C to 150°C, flow)0.0000391/°CISO 11359-2
Coefficient of Thermal Expansion (at 23°C to 150°C, xflow)0.000041/°CISO 11359-2
Ball Pressure Test (at 123°C to 127°C)PassIEC 60695-10-2
Vicat Softening Temperature (Rate B/120)210°CISO 306
Heat Deflection Temperature/Ae (at 1.8 Mpa, Edgew 120*10*4, sp=100mm)190°CISO 75/Ae
Relative Temperature Index (Electrical) ᵖ170°CUL 746B
Relative Temperature Index (Mechanical with impact) ᵖ170°CUL 746B
Relative Temperature Index (Mechanical without impact) ᵖ170°CUL 746B
Electrical Properties
ValueUnitsTest Method / Conditions
High Voltage Arc Track Rate (PLC)2PLC CodeUL 746A
Comparative Tracking Index (UL, PLC)4PLC CodeUL 746A
Hot Wire Ignition (PLC 1)min. 3mmUL 746A
Hot Wire Ignition (PLC 2)min. 1.6mmUL 746A
High Ampere Arc Ignition (PLC 3)min. 3mmUL 746A
High Ampere Arc Ignition (PLC 4)min. 1.6mmUL 746A
Arc Resistance (Tungsten, PLC)6PLC CodeASTM D495
Impact Properties
ValueUnitsTest Method / Conditions
Instrumented Dart Impact Total Energy (at 23°C)380JASTM D3763
Izod Impact (Notched, at 23°C)117J/mASTM D256
Izod Impact (Notched, at -30°C)120J/mASTM D256
Izod Impact (Notched, 80*10*4, at 23°C)10kJ/m²ISO 180/1A
Izod Impact (Notched, 80*10*4, at -30°C)8kJ/m²ISO 180/1A
Charpy Impact (at 23°C, V-notch Edgew 80*10*4 sp=62mm)11kJ/m²ISO 179/1eA
Injection Molding
ValueUnitsTest Method / Conditions
Back Pressure0.3 - 0.7MPa
Drying Temperature135°C
Drying Time4 - 6Hrs
Drying Time (Cumulative)10Hrs
Front - Zone 3 Temperature350 - 370°C
Maximum Moisture Content0.02%
Melt Temperature350 - 370°C
Middle - Zone 2 Temperature345 - 365°C
Mold Temperature135 - 165°C
Nozzle Temperature350 - 370°C
Rear - Zone 1 Temperature340 - 360°C
Screw Speed40 - 70rpm
Shot to Cylinder Size40 - 60%
Vent Depth0.025 - 0.076mm
Flame Characteristics
ValueUnitsTest Method / Conditions
UL Recognized (94-5VA Flame Class Rating) ᵖmin. 1.9mmUL 94
UL Recognized (94V-0 Flame Class Rating) ᵖmin. 0.38mmUL 94
Note

ᵖ UL ratings shown on the technical datasheet might not cover the full range of thicknesses and colors. For details, please see the UL Yellow Card.

 

Regulatory & Compliance

Certifications & Compliance
ULTEM™ Resin May Support
  • Electrical: UL94 V0 & 5VA, UL94 F1, UL746B
  • Telecom: Telcordia GR-326, TIA/EIA-604-10A
  • Mobility: FMVSS, IATF 16949, ISO 14001
  • Food Service: FDA, NSF, EFSA, JHOSPA
  • Water: NSF, WRAS, KTW
  • Semiconductors: FM
  • Healthcare: ISO 10993, FDA, USP Class VI, compatible with multiple sterilization methods
  • Aerospace: ABD 0031, BMS, FAR25.853, OSU 55/55 & NBS smoke density tests

Packaging & Availability

Regional Availability
  • Americas
  • North America
Availability

ULTEM™ resin is available in transparent and opaque custom colors, and can be glass filled for added stiffness.