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GENIOSIL® GF 82

GENIOSIL® GF 82 is an epoxy-functional alkoxysilane. It is a clear, colorless liquid with a characteristic odor similar to gasoline. It hydrolyzes slowly in the presence of water, releasing ethanol, and forms silanols that can react with themselves to produce siloxanes or bind to inorganic substrates. The epoxy group on GENIOSIL® GF 82 can undergo a ring-opening reaction with nucleophiles such as alcohols and amines.

Brand: GENIOSIL (17 products)

Chemical Family: Silanes

Functions: Adhesion Promoter, Coupling Agent

Product Type: Primer

Application Method: Air Knife Coating, Spray

Synonyms: [[3-(Triethoxysilyl)propoxy]methyl]oxirane, [3-(Glycidoxy)propyl]triethoxysilane, [3-(Glycidyoxy)propyl]triethoxysilane, 2-[[3-(Triethoxysilyl)propoxy]methyl]oxirane, 3-(2,3-Epoxypropoxy)propyltriethoxysilane, 3-(2,3-Epoxypropyloxy) propyl triethoxy silane, 3-(Glycidyloxypropyl)triethoxysilane, 3-(Triethoxysilyl)propyl glycidyl ether, 3-Glycydoxylpropyltriethoxysilane, Epoxypropoxypropyltriethoxysilane, Glycidyl 3-(triethoxysilyl)propyl ether, Triethoxy(3-glycidoxypropyl)silane, Triethoxy[3-(2-oxiranylmethoxy)propyl]silane, γ-(2,3-Epoxypropoxy)propyltriethoxysilane, γ-(Glycidyloxypropyl)triethoxysilane, γ-Glycidoxypropyltriethoxysilane, γ-Glycydoxypropyltriethoxysilane

Technical Data Sheet

Enhanced TDS

Knowde-enriched technical product data sheet

Identification & Functionality

Features & Benefits

Applications & Uses

Markets
Applications
Applicable Processes
Application Method
Compatible Polymers & Resins
Compatible Substrates & Surfaces
Use Level
0.5 - 2.5 %
Applications
  • Interior Paints
  • Sealants
  • Adhesives
Application Details

General processing information:

  • GENIOSIL® GF 82 is highly miscible with standard organic solvents, such as alcohols, hydrocarbons and acetone. GENIOSIL® GF 82 is practically insoluble in neutral water. By incorporating a hydrolysis catalyst (e.g. acetic acid), hydrolysis can be greatly accelerated at pH values of 3 to 4. However, at pH values below 4, the epoxy ring may start to open.
  • GENIOSIL® GF 82 in mineral-filled polymers Fillers are treated either with pure GENIOSIL® GF 82 or a solution thereof (e.g. in alcohol or an alcohol/water mix). It may be necessary to pretreat the substrate with water and/ or a catalyst (e.g. ammonia). Subsequent binding of the treated filler, for example to epoxy resins, is preferably effected during the normal crosslinking process.
  • In an alternative procedure referred to as "blending," GENIOSIL® GF 82 is added directly to the polymer - either before the filler is incorporated or at the same time. A prerequisite for the blending process is that GENIOSIL® GF 82 and the polymer are compatible and that the resin and GENIOSIL® GF 82 do not react prematurely.
  • GENIOSIL® GF 82 as a surface modifier Used as a primer, GENIOSIL® GF 82 is applied as a 0.5 - 2.5 percent solution (preferably organic) to an inorganic substrate (e.g. metal or glass surfaces) for example by spraying or knife coating. After GENIOSIL® GF 82  has dried and bonded to the surface (postcure if necessary)techniquanic coating can be applied using a standard e (e.g. spraying, knife coating).
  • In a further application, GENIOSIL® GF 82 can be used together with other hydrolyzable silicon compounds, such as silicates (e.g. SILICATE TES 28), as a constituent of aqueous solgel materials. GENIOSIL® GF 82 is mainly used in the treatment of inorganic fillers (e.g. glass, mineral and glass wools, ATH, kaolin, mica, metallic oxides) for various polymer types, such as epoxy resins, urethane, melamine resins, EPDM, and for polysulfides, as a component of electronic potting compounds, as an additive or primer in coatings, paints, adhesives and sealants, and as a component of inorganic polysiloxane-based coatings.

Properties

Color
Physical Form
Insoluble in
Water
Miscible in
Hydrocarbons, Alcohols, Acetone
Typical Properties
ValueUnitsTest Method / Conditions
Boiling Point (at 13 hPa)143°C-
Density (at 25°C)1.01g/cm³DIN 51757
Dynamic Viscosity (at 25°C)3mPa·sDIN 51562
Epoxy Contentapprox. 15.0%-
Flash Pointmin. 100 °CISO 2719
Ignition Temperature225°CDIN 51794
Puritymin. 96.0 %-
Refractive Index (at 25°C)1.425-DIN 51423
Properties
  • The use of GENIOSIL® GF 82 as a coupling agent in mineral-filled plastics improves filler dispersibility, reduces its sedimentation tendency and greatly lowers the resin's viscosity. In addition, it leads to higher filler loading and a marked increase in water (vapor) resistance, as well as resistance to acids and bases.
  • As a component of adhesives and sealants, GENIOSIL® GF 82 improves both adhesion to the substrate and mechanical properties such as flexural strength, tensile strength and modulus of elasticity. In potting compounds for electronic components, it has a positive influence on properties such as volume resistivity and dielectric constant.
  • An acidic or basic catalyst may be required. As a bifunctional, organically unsaturated molecule, GENIOSIL® GF 82 is able to function as a molecular bridge between inorganic and organic substrates.

Regulatory & Compliance

Packaging & Availability

Country Availability
Regional Availability
  • Africa
  • Asia
  • Europe
  • Latin America
  • North America
  • Oceania