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GENIOSIL® STP-E 10

1 of 3 products in this brand
GENIOSIL® STP-E 10 is a polyether-based silane-terminated polymer suitable as a binder in moisture-curing formulations. It differs from conventional silylated polymers due to its high reactivity, which results from the structural proximity of the nitrogen atom to the silicon atom in the dimethoxy(methyl)silyl-methylcarbamate group (alpha-effect). It hydrolyzes in the presence of moisture to form a stable siloxane network initiated by mild catalysis, rather than heavy metal ions.

Features: Fast Cure, Improved Ageing Resistance, Low Glass Transition Temperature, Multi-Substrate Adhesion, Water Resistance

Technical Data Sheet

Knowde Enhanced TDS

Identification & Functionality

CASE Ingredients Functions
Technologies
Chemical Structure

GENIOSIL® STP-E 10 - Chemical Structure

Features & Benefits

Applications & Uses

Cure Method
Applications
  • Building & Construction Adhesives
  • Do It Yourself
  • Flooring Installation
  • Industrial Adhesives
Application Details

Application

  • GENIOSIL® STP-E10 is used as a reactive binder for sealants and adhesives, potting compounds and coatings.
  • Curing takes place at ambient temperature in the presence of both moisture and catalyst.
  • Depending on the formulation, either prepared as one-part or two-part systems, shows good adhesion to a wide variety of substrates even without pretreatment.
  • The low glass transition temperature allows stable mechanical properties over a wide temperature range.

Processing

  • GENIOSIL® STP-E10 dissolves readily in standard organic solvents. It is virtually insoluble in aqueous media, and reacts slowly releasing methanol and forming a resinous deposit.
  • Despite its highly reactive terminal groups, uncatalyzed GENIOSIL® STP-E10 is stable in air for several days. However, its reactivity with water or atmospheric humidity must be taken into account during storage and processing, since the material will slowly start to condense.
  • GENIOSIL® STP-E10 can be formulated by conventional methods and mixing processes. Its formulation composition depends on the required property profile.
  • GENIOSIL® STP-E10 can be formulated with a variety of fillers. The range starts with oxides, such as aluminum hydroxide, quartz powders or pyrogenic silica, and extends to coated and uncoated chalks.
  • The type and amount depends on the mechanical needs as well the desired thixotropy. Water scavengers can be added to stabilize the formulations against premature curing as this is moisture-curing technology. Therefore exclusion of moisture during compounding and storage is necessary.
  • GENIOSIL® XL 10 or GENIOSIL ® XL 70 are particularly suitable scavengers. Any kind of plasticizer can be used to further lower the viscosity as well as to impact elongation values.
  • It has been observed, that polypropylene glycol types give better mechanical performance whereas aromatic plasticizers like trimellitates or phthalates yield good adhesion values.
  • Antioxidants, UV- and light-stabilizers are mandatory to ensure durable sealants and adhesives. The amount and kind of stabilizer depends on application needs.
  • Curing of GENIOSIL® STP-E10 requires a catalyst that does not necessarily have to be organo-metallic. However dioctyl tin may be used if required. Catalysis can also be accelerated with titanium compounds, as well as inorganic (phosphoric) or organic (tartaric) acids.
  • Primarily, we recommend using an amine catalyst, and adjusting the skin-formation time by varying the amount of aminosilane used. GENIOSIL® GF 9 and GENIOSIL® GF 95 have proven particularly advantageous here.
  • In particular, GENIOSIL® GF 95 can attain improved water resistance, which is further increased by the addition of epoxy silanes.

Surface Treatment

Always apply the formulation to clean and dry surfaces.

Properties

Physical Form
Appearance
Clear liquid
Odor
Slight but characteristic odor
Stable in
Air
Insoluble in
Aqueous media
Typical Properties
ValueUnitsTest Method / Conditions
Density (at 20°C)1.0069g/cm³DIN 51757
Flash Point98°CISO 2719
Ignition Temperature390°CDIN 51794
Methoxy Group Contentapprox. 1.5vol %
Properties

Formulations based on GENIOSIL® STP-E10 are characterized by the following advantages:

  • Simple compounding with conventional auxiliaries
  • Plasticizer free if desirable
  • Tin free
  • Transparent systems
  • Good mechanics
  • Rapid curing
  • Broad adhesion profile
  • Long shelf life

Packaging & Availability

Country Availability
Regional Availability
  • Africa
  • Asia
  • Europe
  • Latin America
  • Middle East
  • North America
  • Oceania